Octadecyl ferulate

Long chain alkyl esters of ferulic acid are common constituents in the family. From the seeds of Hyoscyamus niger even a diester, 1,24-tetracosanediol diferulate could be isolated (Ma et al. 2002). Solanum tuberosum started to accumulate long chain alkyl (mono)esters three to seven days after wound treatment. The alcohol components ranged from hexadecyl (Cj Hjj) to octacosyl (C gHj,) all even numbers plus two esters of odd chain length alkanols [nonadecyl (Cj Hj ), heneicosyl (C jH j)]. The major metabolites were represented by hexadecyl and octadecyl ferulates. The authors suppose that the formation of all these ferulates is temporally and spatially correlated with suberin formation since they were restricted to the wound periderm (Bernards and Lewis 1992). For a coherent account of suberin chemistry interested readers are directed to a review on the macromolecular aromatic domain in suberized tissues (Bernards and Lewis 1998). 

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