O-Toluanilide

Thirty grams (0.14 mole) of o-toluanilide (Note 1) and 20 ml. of dry benzene are placed in a 125-ml. Claisen flask which is fitted with a condenser for distillation under reduced pressure and set in a water bath. The bath is heated to 50°, and 30 g. (0.14 mole) of phosphorus pentachloride is added to the mixture over a period of 10 minutes. The bath is then, heated to 75°... 

F. Araki and K. Yabutani, a,a,0 -Trifluoro-3 -isopropoxy-o-toluanilide (NNF-136) a new fungicide forthe control of diseases caused by Basidiomycetes, in Proceedings of 1981 British Crop Protection Conference on Pests and Diseases, Vol. 1, pp. 3-9 (1981). 

A procedure for the preparation of o-tolualdehyde from o-toluanilide by the Sonn-Miiller method has been published in Organic Syntheses. In addition to the alternative methods of preparation listed there, o-tolualdehyde has been prepared from o-xylyl bromide and hexamethylenetetramine, by the Stephen reduction of o-tolunitrile, and by the procedure of the present preparation. ... 

The a-toluanilide was prepared by the reaction of o-tolyl-magnesiiun bromide with phenyl isocyanate. If the o-toluanilide has been recrystallized from petroleum ether, it may be necessary... 

Benzamide, N-(3-(1-methylethoxy) phenyl)-2-(trifluoromethyl). See a,a,a-Trifluoro-3 -isopropoxy-o-toluanilide Benzamine blue. See Trypan blue Benzamine, 4,4 -methylenebis (3-chloro-2,6-diethyl)-. See 4,4 -Methylenebis (3-chloro-2,6-diethylaniline)... 

Flutolanil Flutolanil. See a,a,a-Trifluoro-3 -isopropoxy-o-toluanilide Flutriafol CAS 76674-21-0... 

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