Nuclear reactions decay series

Delayed Proton and Neutron Decays. By means of a variety of nuclear reactions, as weh as the spontaneous fission of synthetic nucHdes, large numbers of isotopes of some elements have been produced. For example, whereas the only stable isotope of Cs (Z = 55) is Cs (JV = 78), ah of the Cs isotopes from Cs where 77 = 59 and = 0.57 s, to Cs where N = 93 and = 0.13 s, have been observed. At the low mass end of this series, the last proton is only loosely bound, and at the high mass end, the last neutron is only loosely bound. 

We first write conventional nuclear reactions for each step in the decay series. 

Californium is a synthetic radioactive transuranic element of the actinide series. The pure metal form is not found in nature and has not been artificially produced in particle accelerators. However, a few compounds consisting of cahfornium and nonmetals have been formed by nuclear reactions. The most important isotope of cahfornium is Cf-252, which fissions spontaneously while emitting free neutrons. This makes it of some use as a portable neutron source since there are few elements that produce neutrons all by themselves. Most transuranic elements must be placed in a nuclear reactor, must go through a series of decay processes, or must be mixed with other elements in order to give off neutrons. Cf-252 has a half-life of 2.65 years, and just one microgram (0.000001 grams) of the element produces over 170 mhhon neutrons per minute. 

Actinides, the chemical elements with atomic numbers ranging from 89 to 103, form the heaviest complete series in the Periodic Table. They are radioelements, either naturally occurring or synthesized by nuclear reactions. Their predominant practical application depends on the nuclear properties of their isotopes decay, spontaneous or induced fission. Their chemical and physical properties reflect a very complex electronic structure, and their study and understanding are a challenge to experimentalists and theoreticians. 

The second paper of 1940 [3 ], entitled Kinetics of Uranium Chain Decay, is no less significant than the first. This pioneering work yielded a whole series of brilliant results for the first time, the need to take into account the role of delayed neutrons in the kinetics of chain nuclear reactions was shown (it is precisely the delayed neutrons which ensure easy control of nuclear reactors), the influence of heating on the kinetics of a chain process was considered in detail, and a number of conclusions were reached which are of much importance for the theory of reactor control. This same paper predicted the formation in the process of chain fission of new, previously unknown, nuclei which strongly absorb neutrons, a prediction which was later fully confirmed. 

The element francium is formed in the natural radioactive decay series and in nuclear reactions. All its isotopes are radioactive with short half-lives. The ion behaves as would be expected from its position in the group. 

Why do the nuclear reactions in a decay series eventually stop ... 

The majority of the longer-lived transuranic nuclides produced by neutron capture reactions decay primarily by a-emission. Most environmental samples contain radionuclides from the natural uranium and thorium series in concentrations often many times greater than transuranic concentrations. As a result, the chemical problems encountered in these measurements are derived from the requirement that separated trans-uranics should be free of a-emitting natural-series nuclides which would constitute a-spectrometric interferences. Table I lists those transuranic nuclides detected to date in marine environmental samples, together with some relevant nuclear properties. Their relative concentrations (on an activity basis) are indicated although the ratios may be altered by environmental fractionation processes which enrich and deplete the relative concentrations of the various transuranic elements. Alpha spectrometric measurements do not distinguish between 239p Pu, so these are... 

A series of nuclear reactions that begins with an unstable nucleus and results in the formation of a stable nucleus is called a radioactive decay series. As you can see in Figure 25-11, uranium-238 first decays to thorium-235, which in turn decays to protactinium-234. Decay reactions continue until a stable nucleus, lead-206, is formed. 

Many radionuclides cannot attain nuclear stability by only one nuclear reaction. Instead, they decay in a series of disintegrations. A few such series are known to occur in nature. Two begin with isotopes of uranium, and and one begins with Th. All three of these end with a stable isotope of lead (Z = 82). Table 26-4 outlines in detail the... 

Balance the following equations, which represent nuclear reactions in the uranium-238 decay series. 

The disintegration of a radioactive nucleus is often the beginning of a radioactive decay series, which is a sequence of nuclear reactions that ultimately result in the formation of a stable isotope. Table 23.3 shows the decay series of naturally occurring uranium-238, which involves 14 steps. This decay scheme, known as the uranium decay series, also shows the half-lives of all the products. 

It is important to be able to balance the nuclear reaction for each of the steps in a radioactive decay series. For example, the first step in the uranium decay series is the decay of uranium-238 to thorium-234, with the emission of an a particle. Hence, the reaction is... 

Nuclei differ in their stability, and some are so unstable that they undergo radioactive decay. The ratio of the number of neutrons to number of protons (N/Z) in a nucleus correlates with its stability. Calculate the N/Z ratio for (a) Sm (b) Fe (c) °Ne (d) ° Ag. (e) The radioactive isotope decays in a series of nuclear reactions that includes another uranium isotope, and three lead isotopes, Pb, °Pb, and ° Pb. How many neutrons, protons, and electrons are in each of these fi ve isotopes ... 

This is understood to mean that a neutron is absorbed by a nucleus of 13AI and gamma radiation is emitted, resulting in the formation of a product nucleus f Al. The product nucleus of a nuclear reaction can be either stable or radioactive. If the product nuclide is radioactive, it will eventually decay to a different nuclide. The most common modes of decay are emission of alpha particles, beta particles, and gamma rays other particles or radiations can also be emitted in radioactive decay, but they are of little analytical utility and will not be discussed here. Radioactive decay may involve a single-step transformation or may proceed through a series of steps. An example of the former is... 

Some nuclei cannot gain stability by a single emission. Consequently, a series of successive emissions occurs as shown for uranium-238 in A FIGURE 21.3. Decay continues until a stable nucleus—lead-206 in this case—is formed. A series of nuclear reactions that begins with an unstable nucleus and terminates with a stable one is known as a radioactive series or a nuclear disintegration series. Three such series occur in nature uranium-238 to lead-206, uranium-235 to lead-207, and thorium-232 to lead-208. 

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