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Inerts concentration. The reaction might be carried out in the presence of an inert material. This could be a solvent in a liquid-phase reaction or an inert gas in a gas-phase reaction. Figure 2.96 shows that if the reaction involves an increase in the number of moles, then adding inert material will increase equilibrium conversion. On the other hand, if the reaction involves a decrease in the number of moles, then inert concentration should be decreased (see Fig. 2.96). If there is no change in the number of moles during reaction, then inert material has no effect on equilibrium conversion. [Pg.277]

The scan area" field which is white at the start of scanning is painted black during the test so that the inspector will immediately see which areas still remain to be tested. The zone has not been 100% scanned until the entire field is black. If the probe movement is too fast, or if there is no coupling, or if the probe is rotated at too large an angle, there is no change in the color this means that the corresponding zone has not been properly scanned. [Pg.780]

Van der Waals (physical Surface restructuring on No change in surface... [Pg.572]

One assumes the existence of a fluid that obeys Boyle s law (equation (A2.1.4) ) and that, on adiabatic expansion into a vacuum, shows no change in temperature, i.e. for which/yF=/(0) and = 0. (All... [Pg.336]

The conversion from I to II is by the transfer of a proton from one caibon atom to the other. No change in spm pairing. [Pg.333]

For Woodward-Hoffm an allowed thermal reactions (such as the con rotatory ring opening of cyclobulan e), orbital symmetry is conserved and there is no change in orbital occupancy. Hven though bonds are made and broken, you can use the RHFwave fun etion. [Pg.46]

The elements of the F matr ix depend on either the charge densities q or the bond orders p, which in turn depend on the elements of the F matrix. This circular dependence means that we must start with some initial F matrix, calculate eigenvectors, use the eigenvectors to calculate q and p, which lead to new elements in the F matr ix, calculate new eigenvectors leading to a new F matrix, and so on, until repeated iteration brings about no change in the results. The job now is to fill in the elements of the F matr ix. [Pg.250]

At the outset it will be profitable to deal with an ideal solution possessing the following properties (i) there is no heat effect when the components are mixed (ii) there is no change in volume when the solution is formed from its components (iii) the vapour pressure of each component is equal to the vapour pressure of the pure substances multiplied by its mol fraction in the solution. The last-named property is merely an expression of Raoult s law, the vapour pressure of a substance is pro-... [Pg.5]

The mechanism of the reaction la not known with certainty. It is known from studies utilising as tracer that no change in the carbon skeleton occurs during the reaction, and also that unsaturated hydrocarbons can undergo reactions very similar to those of ketones thus both styiene and phenyl-acetylene can react with sulphur and morpholine to produce phenylaceto-thiomorphoUde, hydrolysis of which yields phenylacetic acid ... [Pg.924]

Apply the test to compounds which contain chlorine or bromine. If the compound is a solid, dissolve 0 1 g. in the minimum volume of pure, dry acetone. To 1 ml. of the sodium iodide acetone reagent add 2 drops of the compound (if a hquid) or the acetone solution (if a sohd). Shake and allow to stand at room temperature for 3 minutes. Note whether a precipitate is formed and also whether the solution acquires a reddish-brown colour (liberation of iodine). If no change takes place at rocrm temperature, place the test-tube in a beaker of water at 50°. After 5 minutes, cool to room temperature, and observe whether a reaction has occurred. [Pg.1060]

They found that the rate of hydrolysis depends only on the concentration of tert butyl bromide Adding the stronger nucleophile hydroxide ion moreover causes no change m... [Pg.339]

Equation (3.47) is used with each of the force components given by (3.44). The limits of integration are different for affine deformation under shear at constant volume. In terms of the coordinates shown in Fig. 3.6, there is no change in x, z increases by a, and y decreases by 1/a. [Pg.156]

Although there is no change in the number of molecules, the linear molecule can take on more conformations than the ring hence we expect that AS>0. [Pg.328]

The above-mentioned codes contain requirements for accelerated durabiUty tests. In addition, interlayer manufacturers and laminators expose test samples for several years under extreme weather conditions, eg, the Florida coast and Arizona desert. The laminated products weather extremely well, with no change in the plastic interlayer. Occasionally, clouding is noted around the edges when exposed to high humidity for long periods, but this is reversible. Colored areas of PVB laminates may fade while subjected to extensive uv/solar irradiation, which could cause an appearance issue. This has not, however, been shown to alter the laminate s other performance properties. [Pg.526]


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See also in sourсe #XX -- [ Pg.183 ]




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