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Nitrosyl reactions with

NO is a radical species, but unlike most other radicals, it is not particularly reactive. However, it does react very rapidly with iron to give well authenticated iron-nitrosyls. Reaction with iron is responsible for the activation of guanylate cyclase it may also be responsible for the cytotoxicity of NO and it has been incorporated into a number of analytical procedures for the detection and quantitation of NO. [Pg.59]

Toray. The photonitrosation of cyclohexane or PNC process results in the direct conversion of cyclohexane to cyclohexanone oxime hydrochloride by reaction with nitrosyl chloride in the presence of uv light (15) (see Photochemical technology). Beckmann rearrangement of the cyclohexanone oxime hydrochloride in oleum results in the evolution of HCl, which is recycled to form NOCl by reaction with nitrosylsulfuric acid. The latter is produced by conventional absorption of NO from ammonia oxidation in oleum. Neutralization of the rearrangement mass with ammonia yields 1.7 kg ammonium sulfate per kilogram of caprolactam. Purification is by vacuum distillation. The novel chemistry is as follows ... [Pg.430]

Reaction with concentrated acids provides a preparative route to nitrosyl salts such as N0[HS04], N0[HSe04], N0[C104], and NO[Bp4], e.g. ... [Pg.454]

Seel and Nogradi were probably the first to suspect that the formulation of the thiol as azidodithiocarbonic acid was incorrect. In a study of the reaction of nitrosyl chloride with azides they found that... [Pg.275]

The resulting acid is then converted to caprolactam through a reaction with nitrosyl-sulfuric acid ... [Pg.287]

Bicyclo[2.2.1]hepta-2,5-diene, nitrosyl chloride adduct, 46, 74 reaction with acetic acid to yield nortricyclyl acetate, 46, 74 Bicyclohexyl, 46, 61 Bicyclohexylidene, 47, 34 ejSO-e s-BlCYCLO[3.3.0]OCTANE-2-CAR-BOXYLIC ACID, 47, 10 Bicyclopentadienylidene, octa-chloro-, 46,93... [Pg.122]

N-Nitroso N phenylglycine, 46, 96 reaction with acetic anhydride to yield 3 phenylsydnone, 46, 96 Nitrosyl chloride, addition to bicyclo-[2 2 ljhepta 2,5 diene, 46, 75 2,4-Nonanedione, 47, 92 Nonane, 1,1,3 trichloro-, 46,104 Nortricyclanol, 46, 74 oxidation by chromic acid, 46, 78 Nortricyclanone, 46, 77 Nortncj clyl acetate 46, 74 frombicyclo[2 2 ljhepta 2,5 dieneand acetic acid, 46, 74 saponification of, 46, 75... [Pg.134]

A strain of Escherichia coli produces a naphthotriazole from 2,3-diaminonaphthalene and nitrite that is formed from nitrate by the action of nitrate reductase. The initial product is NO, which is converted by reactions with oxygen into the active nitrosylating agent that reacts chemically with the amine (Ji and Hollocher 1988). A comparable reaction may plausibly account for the formation of dimethylnitrosamine by Pseudomonas stutzeri during growth with dimethylamine in the presence of nitrite (Mills and Alexander 1976) (Figure 2.2f). [Pg.55]

The synthetic utility of the mercuration reaction derives from subsequent transformations of the arylmercury compounds. As indicated in Section 7.3.3, these compounds are only weakly nucleophilic, but the carbon-mercury bond is reactive to various electrophiles. They are particularly useful for synthesis of nitroso compounds. The nitroso group can be introduced by reaction with nitrosyl chloride73 or nitrosonium tetrafluoroborate74 as the electrophile. Arylmercury compounds are also useful in certain palladium-catalyzed reactions, as discussed in Section 8.2. [Pg.1026]

The scheme required to prepare the potent tri-fluoro corticoid cormethasone acetate (292) illustrates the synthetic complexities involved in some of this work. Sequential acetylation of the pregnenolone derivative 278 with first acetic anhydride in pyridine and then acetic anhydride in the presence of tosic acid affords diacetate 279. Reaction of that intermediate with nitrosyl fluoride results initially in addition of the reagent to the 5,6-olefin moiety to afford the fluoro oxime reaction with a second mole of reagent at nitrogen gives the nitroimine derivative 280 passage over alumina serves to hydrolyze the imine function to the corresponding 6-ketone (281). [Pg.194]

A number of gaseous oxyhalides of nitrogen are known, including the types XNO (nitrosonium or nitrosyl halides) with X = F, Cl, or Br, and XN02 (nitryl halides) with X = F or Cl. Nitrosonium halides are prepared by the reactions of halogens and NO. [Pg.488]

Nitrosonium (NO+) is a strong oxidant and the reduction potential to NO has been measured in non-aqueous media (1.67 V vs. SCE in CH3CN), and estimated for water (Eq. (3)) (12,15). NO+ is subject to rapid hydrolysis to nitrite (2H+ + N02 ), and therefore if formed in biological media would be short-lived. However, other less water-sensitive chemical species can act as NO+ donors in reactions leading to the nitrosation of various substrates. For example, the reactions of certain metal nitrosyl complexes with nucleophiles such as R SH can lead to the transfer of NO+ as illustrated in Eq. (4). Such reactions will be discussed in greater detail below. [Pg.205]

The low reactivity of both Cyt111 and Cyt11 toward NO can be attributed to occupation of the heme iron axial coordination sites by an imidazole nitrogen and by a methionine sulfur of the protein (28). Thus, unlike other heme proteins where one axial site is empty or occupied by H20, formation of the nitrosyl complex not only involves ligand displacement but also significant protein conformational changes which inhibit the reaction with NO. However, the protein does not always inhibit reactivity given that Cat and nNOS are more reactive toward NO than is the model complex Fem(TPPS)(H20)2 (Table II). Conversely, the koS values... [Pg.211]

Nucleophilic reactions with coordinated NO are illustrated by the well known reversible reaction of hydroxide ion with the nitrosyl ligand of... [Pg.222]

Selected Reactions of Metal Nitrosyl Compounds with Nucleophiles... [Pg.223]


See other pages where Nitrosyl reactions with is mentioned: [Pg.280]    [Pg.9]    [Pg.74]    [Pg.66]    [Pg.243]    [Pg.318]    [Pg.180]    [Pg.166]    [Pg.32]    [Pg.180]    [Pg.211]    [Pg.215]    [Pg.216]    [Pg.303]    [Pg.303]    [Pg.664]    [Pg.55]    [Pg.161]    [Pg.425]    [Pg.183]    [Pg.818]    [Pg.612]    [Pg.203]    [Pg.220]    [Pg.222]    [Pg.229]    [Pg.246]    [Pg.247]   


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74 nitrosyl chloride, reaction with acids

74 nitrosyl chloride, reaction with aldehydes

74 nitrosyl chloride, reaction with alkenes

74 nitrosyl chloride, reaction with amides

74 nitrosyl chloride, reaction with amines

74 nitrosyl chloride, reaction with imines

74 nitrosyl chloride, reaction with ketones

Cobalt, nitrosyl complexes, reaction with

Cobalt, nitrosyl complexes, reaction with oxygen

Metal carbonyls reaction with nitrosyl complexes

Nitrosyl chloride, reaction with glycals

Nitrosyl complexes reaction with carbon monoxide

Nitrosyl halides reactions with alkenes

Nitrosyl reaction

Nitrosyl reaction with carbon monoxide

Nitrosyl salts, reactions with

Nitrosyl tetrafluoroborate, reaction with

Reaction with nitrosyl chloride

Reactions with nitrosyl fluoride

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