Nitriles metallation

Raman spectroscopy metal in water complexes, 309 Rare earth complexes acetylacetone synthesis, 377 guanidinium, 282 hydroxamic acids, 506 Redox properties bipyridyl metal complexes, 90 Reductive coupling nitrile metal complexes, 265 Resorcinol, 2,4-dinitro-metal complexes, 273 Rhenium complexes acetylacetone, 376 synthesis, 375, 378... [Pg.1095]

In another study, the metal-induced self-assembly of other cage stuctures, in which four platinum(II) or palladium(II) ions serve to link two preorganised (identical) cone-shaped precursors via cis nitrile-metal-nitrile bonds, has been reported. [Pg.217]

When (V-arylimidoyl chlorides are not easily accessible, they can be successfully replaced by A-arylimidates. A-Arylimidates 12 react with a nitrile-metal chloride complex to form 2,4-di-substituted quinazolines 13 in good yields. Since imidates are destroyed by metal chlorides it is essential that the imidate is reacted with a preformed metal chloride-nitrile complex. ... [Pg.66]

Convenient one-pot syntheses of iV-substituted selenoamides from nitriles, metallic selenium, carbon monoxide, water and amines have been developed on the basis of an amino group exchange reaction between the IV-unsubstituted selenoamides formed in situ and the primary or secondary amines. Aromatic or aliphatic, and IV-mono- or IVA -di-substituted selenoamides can be obtained in good yields by this method (Scheme 27). [Pg.479]

Amines and nitriles facilitate the complexation of metals such as Fe, Ti, W, and Ru. In this work, functionalized phenols are attached to the ring, followed by metal complexation. Titanium complexes (36) and (37) are examples. Similar binding chemistry employing Mn is accomplished through a phenyl phosphine moiety in place of the nitrile. Metals also can add to unsaturated bonds yielding new complexes. For example, a... [Pg.333]

Usual adherends Rubber (particularly nitrile), metal, vinyl plastics Fabrics, foils, plastic film laminate, rubber and sponge rubber, wood Plastics, metals, rubber... [Pg.71]

Rubber (particularly nitrile) metal, vinyl plastics... [Pg.844]

Epoxy-nitrile metal bonds with high peel strength. [Pg.9]

Structural films Epoxy-nitrile Metal-metal bonding, honeycomb structures. [Pg.32]

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