Neodymium thermodynamic propertie

In the assessment of the refining performance of uranium, systematic data has been reported for the chemical properties of uranium complex in various alkali chlorides such as LiCl-RbCl and LiCl-CsCl mixtures [3-5], Information on the coordination circumstance of solute ions is also important since it should be correlated with stability. The polarizing power of electrolyte cations controls the local structure around neodymium trivalent Nd " " as an example of f-elements and the degree of its distortion from octahedral symmetry is correlated with thermodynamic properties of NdClg " complex in molten alkali chlorides [6]. On the other hand, when F coexists with Cr in melts, it is well-known that the coordination circumstances of solute ions are drastically changed because of the formation of fluoro-complexes [7-9]. A small amount of F stabilizes the higher oxidation states of titanium and induces a negative shift in the standard potentials of the Ti(IV)ITi(ni) and Ti(III)ITi(II) couples [7, 8], The shift in redox potentials sometimes causes specific electrochemical behavior, for example, the addition of F to the LiCl-KCl eutectic leads to the disproportionation of americium Am into Am " and Am metal [9],... 

Silva, R.J. (1982) Thermodynamic Properties of Chemical Species in Nuclear Waste. Topical Report The Solubilities of Crystalline Neodymium and Americium Trihydroxides, Lawrence Berkeley Laboratory, 57 pp. 

A -aryl Schiff s bases, 59-60, 60/ 61r Nd-Fe-B magnets separation fractional crystallization method, 170 hydrothermal method, 173 leaching process, 170-171 roasting-leaching, 171 selective leaching, 171-172 solvent extraction, 173-175 Nematic columnar phase, 12-13, I2f Nematic phase, 9-10 Neodymium (Nd) structural properties, 281-285 thermodynamic functions... 

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