Nanofiller composites applications

Up to now we considered pol5meric fiiactals behavior in Euclidean spaces only (for the most often realized in practice case fractals structure formation can occur in fractal spaces as well (fractal lattices in case of computer simulation), that influences essentially on polymeric fractals dimension value. This problem represents not only purely theoretical interest, but gives important practical applications. So, in case of polymer composites it has been shown [45] that particles (aggregates of particles) of filler form bulk network, having fractal dimension, changing within the wide enough limits. In its turn, this network defines composite polymer matrix structure, characterized by its fractal dimension polymer material properties. And on the contrary, the absence in particulate-filled polymer nanocomposites of such network results in polymer matrix structure invariability at nanofiller contents variation and its fractal dimension remains constant and equal to this parameter for matrix polymer [46]. 

Nanofillers, carbon nanotubes (CNTs), especially single-walled carbon nanotubes (SWNTs), have attracted a great deal of interest due to their low density, large aspect ratio, superior mechanical properties, and unique electrical and thermal conductivities [1-4], They can find potential applications in many fields, such as chemical sensing, gas storage, field emission, scanning microscopy, catalysis, and composite materials. 

Composites are engineered materials that contain two or more constituents with different properties that remain distinct from one another within the structure. POCs are a subset of the larger polymer composites group. The increased synthesis of POCs with different additives is necessary to satisfy the industrial demand that cannot be fulfilled by pure polymers. Additive materials can be classified as micro-and nanofillers depending on the applications of the composites. The fillers may be further subdivided as natural (plant fibers) or synthetic (glass fibers, CNT, etc.), different shapes (long or short length), flaky, fibrous, and spherical or disk-like [6]. The conventional addition of filler materials lowers the cost and improves the... 

This is Volume 2 of Natural Rubber Materials and it covers natural rubber-based composites and nanocomposites in 27 chapters. It focuses on the different types of fillers, the filler matrix reinforcement mechanisms, manufacturing techniques, and applications of natural rubber-based composites and nanocomposites. The first 4 chapters deal with the present state of art and manufacturing methods of natural rubber materials. Two of these chapters explain the theory of reinforcement and the various reinforcing nanofillers in natural rubber. Chapters 5 to 19 detail the natural rubber composites and nanocomposites with various fillers sueh as siliea, glass fibre, metal oxides, carbon black, clay, POSS and natural fibres ete. Chapters 20-26 discuss the major characterisation techniques and the final ehapter covers the applications of natural rubber composites and nanoeomposites. By covering recent developments as well as the future uses of rubber, this volume will be a standard reference for scientists and researchers in the field of polymer chemistry for many years to come. 

Depending on the distribution of micro/nanofiller in the polymer matrix, the composites may be classified as microcomposites or nanocomposites. These two types of composites differ significantly with respect to their properties. The nanocomposites show improved properties compared to pure polymer or that of microcomposites. It started only back in 1990, when Toyota research group showed that the use of montmorillonite can improve the mechanical, thermal, and flame retardant properties of polymeric materials without hampering the optical translucency behaviour of the matrix. Since then, the majority of research has been focused in improving the physicochemical properties, e.g. mechanical, thermal, electrical, barrier etc. properties of polymer nanocomposites using cost effective and environmental friendly nanofillers with the aim of extending the applications of these materials in automotive, aerospace, construction, electronic, etc. as well as their day to day life use. The improvements in the majority of their properties have invariably been attributed... 

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