Monolayer- and Multilayer-enzyme Assemblies Functionalized with Electron-transfer Mediators

Monolayer- and Multilayer-enzyme Assemblies Functionalized with Electron-transfer Mediators 

Enzyme monolayers can be electrically contacted by using electron mediators 

Nonorganized multilayers of mediator-tethered enzymes have been constructed by cross-linking on an electrode surface [76]. A ferrocene-contacted GOx film was assembled on an Au-electrode by the 

Performed under argon, in phosphate buffer, pH 7, scan rate 10 mV s. Inset calibration curve for the amperometric response to glucose at 0.35 V. [Adapted from S. Kuwabata, T. Okamoto, Y. Kajiya et al.. Anal. Chem. 1995, 67, 1684-1690.] 

Polymer- and Inorganic Matrix-bound Enzymes Contacted by Coimmobilized Mediators 

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