Molybdenum trichloro

Dimethylberyllium Chromium Molybdenum (IV) Trichloro(vinyl)silane... 

Molybdenum(VI) fluoride is a colorless solid with mp 17.5 C, bp 37 °C, and a liquid density of 2.55. It is soluble in l,l,2-trichloro-l,2,2-trifluoroethane (Freon 113) and chlorinated solvents, although it reacts slowly with carbon tetrachloride 18 it cleaves most ethers9 and reacts18 vigorously with carbon disulfide to give sulfur and bis(trifluoromethyl) disulfide. 

Trichloro(tripyridine)chromium(III), synthesis 36 Tris(3-bromoacetylacetonato)chromium(III), synthesis 37 Cyclopentadienyl tricarbonyl hydrides of chromium, molybdenum, and tungsten, synthesis 38 Trichloro(tripyridine)molybdenum(III), synthesis 39 Potassium octacyanotungstate(IV) 2-hydrate, synthesis 40 Chlorine(CP )-labeled thionyl chloride, silicon tetrachloride, boron chloride, germanium (IV) chloride and phosphorus(III) chloride, synthesis 44 Unipositive halogen complexes, synthesis 46 Monopyridineiodine(I) chloride, synthesis 47 Manganese(III) acetylacetonate, synthesis 49 Triiron dodecacarbonyl, synthesis 52... 

Trichloro (tripyridine) molybdenum (III) has been prepared by the reaction of molybdenum(III) chloride with pyridine at 270° for 5 hours in a sealed tube. The preparation described below using potassium hexachloromolybdate-(III) as starting material is carried out at a lower temperature, requires less time, and involves no special apparatus. 

Trichloro(tripyridine)molybdenum(III) is a deep yellow solid, which decomposes at 172 to 182°, yielding free... 

Methylbromoarsines, synthesis 26 Vanadium(III) fluoride, synthesis 27 Sulfur(IV) fluoride, synthesis 33 Peroxydisulfuryl difluoride, synthesis 34 Trichloro(tripyridine)chromium(III), synthesis 36 Tris(3-bromoacetylacetonato)chromium(III), synthesis 37 Trichloro(tripyridine)molybdenum(III), synthesis 39 Uranyl chloride 1-hydrate, synthesis 41 Rhenium(III) iodide, synthesis 50 Potassium hexachlororhenate(IV) and potassium hexa-bromorhenate(IV), synthesis 51 Iron-labeled cyclopentadienyl iron complexes, synthesis 54 Inner complexes of cobalt(III) with diethylenetriamine, synthesis 56... 

Cl8Hi5B3CI3N3, B-Trichloro-N-triphenylborazine, 43B, 819 Cl8H20B2C0N12, Bis(hydrotris(1-pyrazolyl)borato)cobalt(II), 35B, 434 Cl8H24BM0N6O2 f (Diethylbispyrazolylborato)(pyrazolato)(rj -allyl)(dicarbonyl )molybdenum, 39B, 479... 

Cl4H22F12M0N2P2 f Amminebis-(T -cyclopentadienyl)-N-(C-methyl-C-ethyl-ketimino)molybdenum bis(hexafluorophosphate), 41B, 898 C14H2 3CI3O2U, Trichloro-methylcyclopentadieny1-bis(tetrahydrofuran)-uranium(IV), 45B, 954... 

C3iH29Cl3NbP2 2 C7H8, [1,2-Bis(diphenylphosphino)ethane]trichloro-(Tj -cyclopentadienyl)niobium(IV) bistoluene solvate, 45B, 983 C3 2H2oAgBF, 14O12W4, Tetrakis(cyclopentadienyliodotungsten-tricarbon-yDsilver tetrafluoroborate, 43B, 1090 C3 2H2oHg4MOaOi2, (T -Cyclopentadienyl-tricarbonyl-molybdenum)-mercury-molybdenum tetramer, 45B, 984... 

C2ftHs8Cli2Mo3N304, Tris(tetraethylammonium) hydrogen M hydrido-di-M chloro bis(trichloro-molybdenum) aquo-tetrachloro-oxomolybdenum dihydrate, 45B, 1404... 

Internal proton transfer is observed for amido ligands. The reaction between the 1,2-dimethoxyethane adduct of trichloro(carbyne)molybdenum or -tungsten complexes and (trimethylsilyl)aiylamines produces the stable intermediates 20. The latter, however, re-... 

R = Ph) has been prepared via the templated reaction of l,5,9-trichloro-l,5,9-triphosphacyclododecane-molybdenum complex with phenylcopper or diphenyl-cuprate and further liberation by Mo oxidation by I2 [37]. 

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