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Unipositive Halogen Complexes

Dodd and R. L. Robi.nson Experimental Inorganic Chemistry.  [Pg.169]

A common method for the preparation of these compounds involves the reaction of a silver salt with the halogen in a dry, mildly polar solvent such as chloroform, in the presence of the coordinating base, e.g., pyridine or quinoline. The silver salt may be used in the form of its complex with [Pg.169]

Evidence indicates that the adduct of iod ne(I) chloride and pyridine (synthesis 47) contains unipositive iodine stabilized by coordination with pyridine. [Pg.170]

Submitted by R. A. Zingabo and W. B. Witmeb Checked by Alexander I. Popovf [Pg.170]

The chloroform filtrate is separated and transferred to a 1-1. flask, and 500 ml. of dry, low-boiling petroleum ether is added. The pale yellow crystalline precipitate is separated by filtration in a moisture-free atmosphere (Fig. 21) and [Pg.171]


Trichloro(tripyridine)chromium(III), synthesis 36 Tris(3-bromoacetylacetonato)chromium(III), synthesis 37 Cyclopentadienyl tricarbonyl hydrides of chromium, molybdenum, and tungsten, synthesis 38 Trichloro(tripyridine)molybdenum(III), synthesis 39 Potassium octacyanotungstate(IV) 2-hydrate, synthesis 40 Chlorine(CP )-labeled thionyl chloride, silicon tetrachloride, boron chloride, germanium (IV) chloride and phosphorus(III) chloride, synthesis 44 Unipositive halogen complexes, synthesis 46 Monopyridineiodine(I) chloride, synthesis 47 Manganese(III) acetylacetonate, synthesis 49 Triiron dodecacarbonyl, synthesis 52... [Pg.22]

Kleinberg J (1963) Unipositive halogen complexes. Inorg Synth 7 169-176... [Pg.73]


See other pages where Unipositive Halogen Complexes is mentioned: [Pg.169]    [Pg.169]    [Pg.171]    [Pg.173]    [Pg.175]    [Pg.169]    [Pg.169]    [Pg.171]    [Pg.173]    [Pg.175]    [Pg.15]    [Pg.169]    [Pg.175]   


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