Mixed-oxides fibers

Paste Mixing. The active materials for both positive and negative plates are made from the identical base materials. Lead oxide, fibers, water, and a dilute solution of sulfuric acid are combined in an agitated batch mixer or reactor to form a pastelike mixture of lead sulfates, the normal, tribasic, and tetrabasic sulfates, plus PbO, water, and free lead. The positive and negative pastes differ only in additives to the base mixture. Organic expanders, barium sulfate [7727-43-7] BaSO carbon, and occasionally mineral oil are added to the negative paste. Red lead [1314-41 -6] or minium, Pb O, is sometimes added to the positive mix. The paste for both electrodes is characterized by cube weight or density, penetration, and raw plate density. 

Electrically-conducting Ti02 pigments have been produced by an aftertreatment to give a coating of mixed oxides of indium and tin, or antimony and tin [2.62]. These pigments are applied to fibers used in photosensitive papers for electrophotography, and for the production of antistatic plastics. 

For Saffil alumina fiber, aluminum oxychloride [Al2(OH)jCI] is mixed with a medium molecular weight polymer such as 2wt% polyvinyl alcohol. The aqueous phase contains an oxide sol and an organic polymer. The sol is extruded as filaments into a coagulating (or precipitating) bath in which the extruded shape gels. The gelled fiber is then dried and calcined to produce the final oxide fiber. This solution is slowly evaporated in a rotary evaporator imtil a viscosity... 

Thus far, the oxidation/corrosion behavior of materials which are nominally single phase, and form scales which are nominally single phase oxides has been discussed. In practice, composite materials are often desired to enhance mechanical properties or to improve other properties of the materials such as thermal conductivity, electrical conductivity, as well as oxidation resistance. In these cases, multi-phase materials are developed to enhance the desired properties. When these materials are subjected to high temperature oxidizing environments, the resulting oxidation products are also more complex. In general oxidation results in three classes of scales mixed oxides, compound oxides, or solution oxides. Examples of each will be discussed below. In addition, fiber reinforced composites are a special class of composite materials in which an interphase material is required between the fiber and the matrix to provide the required fracture toughness. The unique issues with these materials will also be discussed. 

An attempt has been made to minimize mathematical expressions presented in this work. Nevertheless, some arithmetic is necessaiy to understand phosphate chemistry as practiced in preparations of phosphate fibers. As a result of Berzelius notations, both silicate and phosphate chemistries are based, to a large extent, upon mixed oxides and ratios of these oxides. In phosphate chemistry R represents a molar ratio ... 

Oxidation Catalysis. The multiple oxidation states available in molybdenum oxide species make these exceUent catalysts in oxidation reactions. The oxidation of methanol (qv) to formaldehyde (qv) is generally carried out commercially on mixed ferric molybdate—molybdenum trioxide catalysts. The oxidation of propylene (qv) to acrolein (77) and the ammoxidation of propylene to acrylonitrile (qv) (78) are each carried out over bismuth—molybdenum oxide catalyst systems. The latter (Sohio) process produces in excess of 3.6 x 10 t/yr of acrylonitrile, which finds use in the production of fibers (qv), elastomers (qv), and water-soluble polymers. 

The 3M Company manufactures a continuous polycrystalline alurnina—sihca—boria fiber (Nextel) by a sol process (17). Aluminum acetate is dissolved in water and mixed with an aqueous dispersion of colloidal sihca and dimethylform amide. This mixture is concentrated in a Rotavapor flask and centrifuged. The viscous mixture is then extmded through spinnerettes at 100 kPa (1 atm) the filaments are collected on a conveyor and heat-treated at 870°C to convert them to metallic oxides. Further heating at 1000°C produces the 10-p.m diameter aluminum borosihcate fibers, which are suitable for fabrication into textiles for use at temperatures up to 1427°C. 

Partial oxidation of propylene results in acrolein, H2C=CHCHO, an important intermediate for acrylic acid, H2C=CHCOOH, or in the presence of NH3, in acrylonitrile, H2C=CHCN, the monomer for acrylic fibers. Mixed metal oxides are used as the catalysts [B.C. Gates, Catalytic Chemistry (1992), Wiley, New York]. 

When multicomponent alkoxide solutions, or a single alkoxide and a soluble inorganic salt, are mixed, a multicomponent alkoxide may result. In this way, such complex oxides such as the YBCO superconductor (cf. Section 6.1.2.4) can be formed. Sol-gel processing can also be used to coat fibers for composites and to form ceramics with very fine pore sizes called xerogels. A xerogel commonly contains 50-70% porosity, a pore size of 1-50 nm, and a specific surface area exceeding 100 m /g. 

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