Microporous organic polymers

Microporous Organic Polymers Design, Synthesis, and Function 5... 

However, the preparation of latex particles may be perceived as having reached a level at which the potential for a fundamental breakthrough in the final materials per se is rather limited. Pioneering efforts may instead be expected in the development of polymeric microcompartmentalized materials. This development, in a limited form, may be exemplified by the work of Gan and colleagues [28], who polymerized organic monomers solubilized in bicontinuous microemulsions and obtained microporous organic polymers. This area is, of course, of future interest, but the problem of lack of correlation between the microemulsion colloidal structure and the microstructure of the final material may result in a focus on the polymerization of liquid crystalline material where even complex systems [29,30] have been shown to retain their microstructure after polymerization. This area of polymerization has been further developed and systematized by Antonietti [31,32], Antonietti et al. [33], and Fendler [34]. 

Dawson R, Cooper Al, Adams DJ (2013) Chemical functionalization strategies for ctubon dioxide capture in microporous organic polymers. Polym Int 62 345—352... 

Microporous Organic Polymers for Carbon Dioxide Capture... 

Xu S, Luo Y, Tan B (2013) Recent development of hypercrossUnked microporous organic polymers. Macromol Rapid Commun 34 471-484... 

Dawson R, Stockel E, Holst JR et al (2011) Microporous organic polymers for carbon dioxide capture. Energy Environ Sd 4 4239-4245... 

Layboum A, Dawson R, Qowes R et al (2012) Branching out with aminals microporous organic polymers from difunctional monomers. Polym Chem 3 533-537... 

Xu C, Hedin N (2013) Synthesis of microporous organic polymers with high C02-over-N2 selectivity and CO2 adsorption. J Mater Chem A 1 3406—3414... 

Farha OK, Spokoyny AM, Hauser BG et al (2009) Synthesis, properties, and gas separation studies of a robust diimide-based microporous organic polymer. Chem Mater 21 3033-3035... 

Sun L, Liang Z, Yu J et al (2013) Luminescent microporous organic polymers containing the l,3,5-tri(4-ethenylphenyl)benzene unit constructed by heck coupling reaction. Polym Chem 4 1932-1938... 

The book Porous Materials for Carbon Dioxide Capture is aimed at providing researchers with the most pertinent and up-to-date advances related to the fields of porous materials design and fabrication and subsequent evaluation in innovative cyclic CO2 adsorption processes, with special emphasis on uncovering the relationships between structural characteristics and CO2 capture performance. The book is divided into seven chapters that provide a resume of the current state of knowledge of porous CO2 capture materials, which include ionic liquid-derived carbonaceous adsorbents, porous carbons, metal-organic frameworks, porous aromatic frameworks, microporous organic polymers, sorption techniques such as cyclic calcination and carbonation reactions, and membrane separations. 

Patra A, Koenen JM, Scherf U (2011) Fluorescent nanoparticles based on a microporous organic polymer network fabrication and efficient energy transfer to surface-bound dyes. Chem Commun 47 9612-9614... 

Recent Developments of Hypercrosslinked Microporous Organic Polymers... 

All of these synthetic methodologies aimed at developing novel microporous organic polymers with larger specific surface areas, precisely controlled pore sizes and multitudinous functions. However, the transition or noble metal catalysts used in the synthesis of CMPs, PAFs and some other MOPs are expensive and rare, which limit the practical applications. Therefore, the sustainable industrial production of microporous organic polymers is still an unsolved challenge. 

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