Methylphenyl sulfide

The product is stable for months when mixed with a small amount of the radical inhibitor, 3-tert-butyl-4-hydroxy-5-methylphenyl sulfide, and stored in a freezer. In the absence of the inhibitor, it isomerizes to a mixture of E- and Z-isomers over a period of some months. 

J-tert-Butyl-4-hydroxy-5-methylphenyl sulfide o-Cresol, 4,4 -thiobis[6-tert-butyl- (8), Phenyl, 4,4 -thiobis[2-(1,1-dimethylethyl)-6-methyl- (9),... 

Upon heating p-toluidine with sulfur at MO0 in the presence of litharge, the so-called thio-p-toluidine is formed. It was shown to be bis- (2-amino-5-methylphenyl) sulfide by deamination and subsequent oxidation to the crystalline sulfone 140... 

SYNS BIS(3-tert-BU1TL-4-HYDROXY-6-METHYL-PHENYL) SULFIDE BIS(4-HYDROXY-5-tert-BUTyL-2-METHYLPHENYL) sulfide DISPERSE MB-61 SANTONOX SANTOVC HITE CRYSTALS THIOALKOFEN BM 4 4,4 -THIOBIS(2-tert-BUTYL-5-METHYLPHENOL) 4,4 -THIOBIS(6-tert-BUTYL-3-METHYLPHENOL) 4,4 -THIOBIS(3-METHYL-6-tert-BUTYLPHENOL) l,l -THIOBIS(2-METHYL-4-HYDRO-XY-5-tert-BUTYLBENZENE) USAFB-15 YOSHINOX S... 

BIS(2-BUTYL)ETHER see BRH760 BIS(3-tert-BUTYL-4-HYDROXY-6-METHYLPHENYL) SULFIDE see TFC600 a-a -BIS(tert-... 

BIS(2-HYDROXY-3-tert-BUTYL-5-ETHYLPHENYL)METHANE see MJN250 BIS(4-HYDROXY-5-tert-BUTYL-2-METHYLPHENYL) SULFIDE see TFC600... 

To test this conclusion, the decomposition of tetraniethyl-1,1,1- 3-ammonium thiophenoxide was studied 111K The decomposition of the dry salt was carried out on a vacuum line giving a 3 to 1 mixture of pure methylphenyl sulfide and trideuteromethylphenylsulfide without any proton scrambling. 

Beilstein Handbook Reference) Antage Crystal Antioxidant AO Antioxidant TMB 6 Bis(3-tert-butyl-4-hydroxy-6-methylphenyl) sulfide BRN 1147776 CCRIS 4917 Disperse MB-61 EINECS 202-525-2 HSDB 5304 Nocrac 300 Nonflex BPS NSC 35388 Rutenol Santonox Santonox BM Santonox R Santowhite crystals Santox Sumilizer WX Sumilizer WX-R Thioalkofen BM 4 Thioalkofen BMCH Thioalkofen MBCH Thioalko-phene BM-4 Ultranox 236 USAF B-15 Yoshinox S Yoshinox SR, Antioxidant for use in adhesives, rubber articles for repeated use, polymers include polyolefins, PVC, xrylic ethyl cellulose antioxidant for lubricants, cutting oils, water-sol. oils, hydraulic oils. Solid mp = 161-164° insoluble in H2O. GE Silicones. 

SYNONYMS antioxidant ao, bis (4-hydroxy-5-tert-buyl-2-methylphenyl)sulfide, 4,4 -thiobis(3-methyl-6-tert-butylphenol), l,r-thiobis(2-methyl-4-hydroxy-5-tert-butylbenzene). 

Another common oxidizing agent is sodium m-periodate (NaI04). Leonard used sodium periodate to oxidize methylphenyl sulfide to the sulfoxide in near-quantitative yield. l In that report, many methods were summarized for oxidizing sulfides, including nitric acid, hydrogen peroxide, chromic acid, ozone, peroxyacids. 

The tandem ylide generation/[2,3]-sigmatropic rearrangement can also be performed with sulfur and iodonium ylides and in these cases the reaction can proceed in intermolecular fashion.For example, up to 78% ee has been obtained in the reaction of allyl-2-methylphenyl sulfide (9.129) with aryl diazoacetates such as (9.130) in the presence of the copper catalyst generated with bis-oxazoline (9.07), while the reaction of aUyl iodide (9.132) with ethyl diazoacetate yields product (9.133) with 69% ee using this complex. ... 

Bis (4-hydroxy-5-t-butyl-2-methylphenyl) sulfide. See 4,4 -Thiobis-6-(t-butyl-m-cresol)... 

Synonyms Bis (3-t-butyl-4-hydroxy-6-methylphenyl) sulfide Bis (4-hy-droxy-5-t-butyl-2-methylphenyl) sulfide 4,4 -Thiobis (2-t-butyl-5-methylphenol) 4,4 -Thiobis (6-t-butyl-3-methylphenol) 4,4 -Thiobis (6-t-butyl-3,3-methylphenol) 4,4 -Thiobis (3-methyl-6-t-butylphenol) 1,1 -Thiobis (2-methyl-4-hydroxy-5-t-butylbenzene)... 

Bis (p-hydroxy) benzophenone. See 4,4 -Dihydroxybenzophenone Bis (2-hydroxy-3-t-butyl-5-ethylphenyl) methane. See 2,2 -Methylenebis (4-ethyl-6-t-butylphenol) Bis (4-hydroxy-5-t-butyl-2-methylphenyl) sulfide. See 4,4 -Thiobis-6-(t-butyl-m-cresol) Bis-2-hydroxy-5-chlorophenyl) methane. See Dichlorophene... 

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