Methyl ethoxyacetate

Diethoxymethane is the main product obtained at lower temperature (130 °C), whereas methyl ethyl ether, methanol, ethyl propionate and ethoxyacetic derivatives predominate at higher temperature (170 C). Diethylcarbonate, always present among the reaction products, is obtained, however, only in low yields (2-3%). [Pg.233]

Aliphatic alcohols and benzyl alcohol are oxidized by Ph3Bi(OOtBu)2 to the corresponding carbonyl compounds (Equation (141)).233 It has been suggested that the oxidation occurs via dehydrogenation of alcohols by phenyl or tert-butoxy radical. When treated with diethyl ether, Ph3Bi(OOtBu)2 oxidizes the methyl group to afford ethoxyacetic... [Pg.451]

C14H220 alpha-irone 79-69-6 527.81 46.562 2 27814 C14H2603 5-methyl-2-isopropylcyclohexyl ethoxyacetate 579-94-2 542.65 47.997 2... [Pg.526]

Ph3Bi(OOtBu)2 oxidizes a methyl group in diethyl ether to afford ethoxyacetic acid as the initial product [350], The peroxide also oxidizes toluene and ethylbenzene to benzaldehyde and acetophenone, respectively, via radical intermediates [343]. Thiophenol, benzophenone hydrazone, and hydrazobenzene are efficienfly oxidized by organobismufh(V) compounds [341a, c]. 2,6-Dialkylphenols are oxidatively dimerized by PhsBiCOs [300e]. [Pg.799]

Ethoxyacetic acid Ethylene glycol acetate Glyceryl formal Methyl lactate Methyl-(S)-lactate C4H8O4 Erythrulose C4H8O4 Pd Palladium diacetate C4H8O4S Thiolanediol C4H8S... [Pg.7033]

Methyl-2-isopropylcyclohexyl ethoxyacetate, (1a,2 3,6a) 1-Methyl-4-isopropyl-2-nitrobenzene... [Pg.460]

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