Methyl dichloroacetate

Sodium (3-Nitroethanol Methyl dichloroacetate Acetic anhydride... 

Methyl- 1-cyclopentene 3- Methyl-1-cyclopentene 4- Methyl-1-cyclopentene Methyl cyclopropanecarboxylate 2-Methyldecane 4-Methyldecane Methyl decanoate Methyl dichloroacetate Methyldichlorosilane Methyl 2,2-dimethylpropanoate 2-Methyl-1,3-dioxane 4-Methyl-1,3-dioxane 4-Methyl-l,3-dioxolan-2-one 9.62... 

The coupling of methyl dichloroacetate with acetophenone or cyclohexanone leads to high yields (75-80%) of epoxides under similar reaction... 

Basic cleavage of the dithiolothiadiazolone 40 followed by treatment with methyl dichloroacetate yielded the ester 106 106 was employed as a key starting material for synthesis of unsymmetrical TTF derivatives (Scheme 8) <1996JOC3987>. 

Methyl formate Methyl acetate Methyl propionate Methyl isobutyrate Methyl difluoroacetate Methyl trifluoroacetate Methyl monochloroacetate Methyl dichloroacetate Ethyl trichloroacetate Methyl trichloroacetate Methyl cyanoacetate Methyl methoxyacetate Methyl benzoate... 

Pyrrolizidines and indolizidines may be prepared by reaction between the electrogenerated anion of methyl dichloroacetate and acylated a-aminoaldehydes, obtained from amino acids. High diastereoselectivity (> 99%) was observed in the reaction of some cyclic a-aminoaldehydes [137]. 

At high temperatures, [Ru(CH3)(Tp)(CO)(NCMe)] acts as catalyst for the production of polystyrene. The dependence of polystyrene molecular weight on benzene/cumene molar ratios suggests a radical polymerization mechanism. The polymerization of methyl methacrylate, in the presence of [Ru(CH3)(Tp)(CO)(NCMe)j with carbon tetrachloride or methyl dichloroacetate, has been observed at 90°C.31... 

METHYL DICHLOROACETATE (116-54-1) CJH4CI2O2 Combustible, water-reactive liquid (flash point 176°F/80°C). Contact with water causes heat and decomposition to corrosive dichloroacetic acid. Aqueous solution is an acid. Incompatible with sulfuric acid, alkalis. 

Much effort towards stereoselective synthesis of 3-deoxy-2-ulosonic acids resulted in the development of several strategies based on the diverse building units. Among them aldol reaction between D-arabinose derivative 50 and methyl dichloroacetate (51) deserves some attention [78] (Scheme 14). The condensation product isolated as oxirane derivative 52 reacted smoothly with Mgk to give the intermediate 53, easily convertible into 3-deoxy-D-ara6mo-2-heptulosonic acid methyl ester 56 in high yield. 

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