Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Detection limits method

The method detection limit (MDL) is the smallest quantity or concentration of a substance that a particular instrument can measure (Patnaik, 2004). It is related to the instrument detection limit (IDL), which depends on the type of instrument and its sensitivity, and on the physical and chemical properties of the test substance. [Pg.182]

The method detection limit is, in reality, a statistical concept that is applicable only in trace analysis of certain types of substances, such as organic pollutants by gas chromatographic methods. The method detection limit measures the minimum detection limit of the method and involves all analytical steps, including sample extraction, concentration, and determination by an analytical instrument. Unlike the instrument detection limit, the method detection limit is not confined only to the detection limit of the instrument. [Pg.182]

In the environmental analysis of organic pollutants, the method detection limit is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero and is [Pg.182]

and Roessler, E. B. 1972. Introduction to Probability and Statistics. W.H. Freeman, San Francisco. [Pg.183]

Annual Book ofASTM Standards. American Society for Testing and Materials, West Conshohocken, PA. [Pg.183]


A method for the analysis of lead in industrial wastewater has a method detection limit of 10 ppb. The relationship between... [Pg.722]

The linear dynamic range of this method is 0.1 p.gl to 100 J.gl i The method detection limit (MDE) depends on selected operating conditions and a calibration range. It is important to use high purity reagents in all determinations. [Pg.211]

Sample matrix Preparation method Analytical method detection limit Percent recovery Reference... [Pg.230]

The method detection limit (MDL) is a term that should be applied to extraction and analysis methods developed for the analysis of specific analytes within a matrix. The MDL can be defined as the smallest amount of an analyte that can be reliably... [Pg.63]

Seven replicate recoveries of flucarbazone-sodium, sulfonic acid, sulfonamide and NODT from well water fortified af 50 ng L averaged 106,100,89 and 106%, respec-fively. Therefore, the LOQ is 50 ng L for each analyte. The method detection limits for flucarbazone-sodium, sulfonic acid, sulfonamide and NODT, as determined by the United States Environmental Protection Agency (USEPA) recommended technique, are 5, 11, 20 and 19ngL, respectively. [Pg.495]

Environmental Protection Agency Instruction 10 CFR Ch. 1 (7-1-94 Edition) Appendix B to Part 136 - Definition and Procedure for the Determination of the Method Detection Limit - Revision 1.11, US Environmental Protection Agency, Washington, DC (1994). [Pg.497]

The determination of the LQD and LQQ is an important aspect of any method used for water analysis. A review article by Keith" outlines many of the issues concerning the determination of method detection limits. In general, the determination of the... [Pg.833]

Sample matrix Sample preparation Analytical method Detection limit Accuracy Reference... [Pg.200]

Purification methodologies for estrogens have been carried out by SPE with C18 [53, 54], polymeric [56, 60-62], silica [56-59] and anion exchange materials [59], preparative LC [53, 62], gel permeation chromatography (GPC) [54, 59, 97], liquid-liquid extraction [56], combination of them, or simple filtration [51]. However, the latter corresponds to the method with the highest reported method detection limits (MDL) [up to 175 ng/g dry weight (dw)]. [Pg.51]

How do you distinguish between the instrument detection limit (IDL) and the method detection limit (MDL) ... [Pg.87]

Arc/spark emission methods have been widely used for the determination of metals and some non-metals particularly as minor and trace constituents. In recent years, however, the technique has been extensively displaced by atomic absorption spectrometry, and plasma emission methods. Detection limits for many elements are of the order of 1-10 ppm (Table 8.3) and as... [Pg.293]

Of the 53 elements determined, 48 had useful values above the method detection limits. The data for As and Cr are shown as dotplots (Figs. 1 and 2) as examples of metals and metalloids that occur in both soluble and acid-resistant mineral phases. Dotplots highlight the varying analytical precision for each material and each analytical protocol. [Pg.177]

Method detection limit (MDL) in reagent water. Estimated quantitation limits for other matrices are 10 MDL in groundwater, 670-10,000 MDL in soil, and 100,000 MDL in nonaqueous wastes. [Pg.141]

The ratios of relative concentration can not be calculated because the heavy metal contents of rice or vegetables growing in an acidic rain area or in a non-acidic rain area is lower than the method detection limit (MDL) of heavy metals. [Pg.358]

Osemwengie et al. [14] NMs, PCMs, and nitromusk metabolites Wastewater effluent U.S. - On-site 60-L extraction with NEXUS sorbent - Silica gel and gel-permeation chromatography - GC-MS - Recovery=80-97% method detection limit =0.02-0.3 ng/L... [Pg.87]


See other pages where Detection limits method is mentioned: [Pg.393]    [Pg.235]    [Pg.41]    [Pg.319]    [Pg.234]    [Pg.524]    [Pg.76]    [Pg.63]    [Pg.83]    [Pg.607]    [Pg.610]    [Pg.610]    [Pg.818]    [Pg.834]    [Pg.622]    [Pg.158]    [Pg.24]    [Pg.33]    [Pg.314]    [Pg.211]    [Pg.217]    [Pg.440]    [Pg.78]   
See also in sourсe #XX -- [ Pg.319 ]

See also in sourсe #XX -- [ Pg.158 ]

See also in sourсe #XX -- [ Pg.97 , Pg.178 ]

See also in sourсe #XX -- [ Pg.46 , Pg.215 , Pg.241 ]

See also in sourсe #XX -- [ Pg.319 ]

See also in sourсe #XX -- [ Pg.319 ]

See also in sourсe #XX -- [ Pg.278 ]

See also in sourсe #XX -- [ Pg.293 ]

See also in sourсe #XX -- [ Pg.412 ]




SEARCH



Analytical methods detection limits

Analytical methods limits of detection

Destructive sample preparation methods detection limit

Detectable limit

Detection limits

Detection limits, limitations

Detection methods

Detection-limiting

Electrochemical methods detection limits

Limit method

Method detection limit, MDL

Method limit of detection

Method limitations

Statistical methods detection limit

© 2024 chempedia.info