Metal-Organic Framework Compounds

Mendt M, Jee B, Stock N et al (2010) Structural phase transitions and thermal hysteresis in the metal-organic framework compound MlL-53 as studied by electron spin resonance spectroscopy. J Phys Chem C 114 19443-19451... 

Poppl A, Kunz S, Himsl D et al (2008) CW and pulsed ESR spectroscopy of cupric ions in the metal-organic framework compound Cu3(BTC)2. J Phys Chem C 112 2678-2684... 

Henschel A, Gedrich K, Kraehnert R, Kaskel S. Improved synthesis, thermal stability and catalytic properties of the metal-organic framework compound CUj(BTC)j. Chem Commun 2008 4192-4. 

Gonzalez J, Devi RN, TunstaU DP, Cox PA, Wright PA. Deuterium NMR studies of framework and guest mobility in the metal—organic framework compound MOF-5, Zn OfO CC H CO lj. Microporous Mesoporous Mater 2005 84 97-104. 

Hoffmann HC, Dehowski M, Muller P, Paasch S, Senkovska I, Kaskel S, et al. Solid-state NMR spectroscopy of metal-organic framework compounds (MOFs). Materials 2012 5 2537-72. 

N anomaterials have been around for hundreds of years and are typically defined as particles of size ranging from 1 to 100 nm in at least one dimension. The inorganic nanomaterial catalysts discussed here are manganese oxides and titanium dioxide. Outside the scope of this chapter are polymers, pillared clays, coordination compounds, and inorganic-organic hybrid materials such as metal-organic frameworks. 

The large field of supramolecular coordination chemistry could be divided into polymers [1-5] and discrete compounds [6-10]. Coordination polymers or metal organic frameworks (MOF) are not only described in the literature but are also... 

The search for new zeolite-like structures was initially extended to aluminophosphate-based molecular sieves,3 and these explorations produced a variety of exotic compounds with open-framework structures, which include besides metal phosphates,4 carboxylates,5 sulfates,6 selenites, and selenates.7 Growth of this area has been rapid in the past decade necessitating new editions of the Atlas of Zeolites.2 It is noteworthy that metal—organic framework (MOF) solids have been included as zeolite types in the latest edition of the Atlas of Zeolites. 

IINS spectroscopy is an important tool for development of understanding of the interactions between the substrate and the adsorbate in hydrogen-storage materials. In addition to carbon nanotubes 17a,b,c), activated carbon 17d), and several other materials are being actively investigated. These include metal organic framework (MOF) compounds 18b,c), zeolites 18d), and metal phosphates 18e). 

Figure 2.46 Molecular structure of [ Nd(L °)3(THF) 2(ir-bpm)],hydrogen atoms are omitted. Displacement ellipsoids are drawn at the 50% prohahihty level [26a]. (Reprinted with permission from G. Zucchi, O. Maury, R Thuery and M. Ephritikhine, Structural diversity in neodymium hipyrimidine compounds with near infrared luminescence from mono- and binuclear complexes to metal-organic frameworks, Inorganic Chemistry, 47, 10398-10406, 2008. 2008 American Chemical Society.)...

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