Metal complexes clusters

Figure 13.24 Structure of the cubane-like mixed metal-metal cluster complex [Sb4- Co(CO)3l4].

The hydrido-transition metal cluster complexes. A. P. Humphries and H. D. Kaesz, Prog. Inorg. Chem, 1979, 25,145-222 (244). 

Recent advances in the vibrational spectroscopy of metal cluster complexes. I. A. Oxton, Rev. Inorg. Chem., 1982,4, 1-26 (107). 

Electronic structures of transition metal cluster complexes. M. C. Manning and W. C. Trogler, Coord. Chem. Rev., 1981, 38, 89-138 (406). 

The electronic structure of transition metal cluster complexes with weak- and strong-field ligands. G. P. Kostikova and D. V. Korol kov, Russ. Chem. Rev. (Engl. Transl.), 1985,54, 344 (137). 

Lewis LN (1998) In Adams RD, Cotton FA (eds) Catalysis by di- and polynuclear metal cluster complexes. Wiley-VCH, Weinheim p 373... 

There has been great interest in the preparation of bimetallic transition metal cluster complexes containing palladium.899-902 Bimetallic palladium-ruthenium clusters have been shown to be good precursors to supported bimetallic catalysts.903,904... 

Moiseev, I. I. Vargaftik, M. N. Catalysis with palladium clusters. In Catalisis by Di- and Polynuclear Metal Cluster Complexes Adams, R. D. Cotton, F. A. Eds. Wiley VCH New York, 1998, p 395. 

TREVOR AND KALDOR Gas-Phase Transition Metal Cluster Complexes... 

Photofragmentation of Transition Metal Cluster Complexes in the Gas Phase... 

The gas phase photofragmentation of transition metal cluster complexes is discussed. The information available for the gas phase dissociation of... 

Presently, the gas phase photofragmentation of several transition metal cluster complexes is reviewed. The techniques employed for these gas phase studies rely on sensitive ionization detection and the use of a broad range of excitation energies. 

The information available is discussed in light of the effects of excitation energy and the environment on the photofragmentation process of several transition metal cluster complexes. The photochemical information provides a data base directly relevant to electronic structure theories currently used to understand and predict properties of transition metal complexes (1,18,19). 

In this paper, the photofragmentation of transition metal cluster complexes is discussed. The experimental information presented concerning the gas phase photodissociation of transition metal cluster complexes comes from laser photolysis followed by detection of fragments by ionization (5.). Ion counting techniques are used for detection because they are extremely sensitive and therefore suitable for the study of molecules with very low vapor pressures (6.26.27). In addition, ionization techniques allow the use of mass spectrometry for unambiguous identification of signal carriers. 

IV. Metal Cluster Complexes Derived from 1,3-Diynes or Poly-ynes. 130... 

METAL CLUSTER COMPLEXES DERIVED FROM 1,3-DIYNES OR POLY-YNES... 

Many examples of metal cluster complexes featuring diyne or higher poly-yne ligands are known, and have generally been obtained by three main routes. 

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