Palladium complexes mixed-metal clusters

Imido dialkyl complexes, with tantalum, 5, 120 Imido-dicarbenes, with palladium, 8, 228-229 Imido groups, in Ru-Os mixed-metal clusters, 6, 1078 Imido hydrocarbyl complexes, with Re(VII), 5, 945 Imido ligands... 

The first mixed-metal cluster of Os-Pd, [Os6Pd(bipy)(CO)i8], was reported in 1994, and since then a variety of mixed-metal cluster that contain various Os Pd ratios have been created. Palladium-pyridine complexes appear to be useful reagents in the synthesis of mixed-metal clusters with osmium carbonyl compounds. " The reaction of the coordinately unsaturated cluster [Os3(yu-H)2(CO)io] with [Pd(NH3)2l2] afforded a number of Os-Pd clusters with a high hydride content. " Both palladium phosphine and bidentate phosphine complexes are useful in the preparation of high-nuclearity mixed-metal clusters. The reaction of [Os3(/i-H)2(CO)io] with [Pd2(/i-dppm)2Cl2] gave 258 and 259, in addition to 260, with the same metal core, " in which the molecule contains a twofold symmetry axis. " " ... 

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