Martensite metal

Mittemeijer E J, Cheng L, der Schaaf P J V, Brakman C M and Korevaar B M 1988 Analysis of nonisothermal transformation kinetics tempering of iron-carbon and iron-nitrogen martensites Metall. Trans. A 19 925... 

E. J. Mittemeijer, Liu Cheng, P. J. van der Schaaf, C. M. Brakman, and B. M. Korevaar. Analysis of non-isothermal transformation kinetics tempering of iron-carbon and iron-nitrogen martensites. Metall. Trans. 19A, 925 (1988). 

Gen] Van Genderen, M.J., Isac, M., Boettger, A., Mittemeijer, E.J., Aging and Tempering Behavior of Iron-Nickel-Carbon and Iron-Carbon Martensite , Metall. Mater. Trans. A, 28(3), 545-561 (1997) (Experimental, Kineties, Phase Relations, 51)... 

The enhanced strength and corrosion properties of duplex stainless steels depend on maintaining equal amounts of the austenite and ferrite phases. The welding thermal cycle can dismpt this balance therefore, proper weld-parameter and filler metal selection is essential. Precipitation-hardened stainless steels derive their additional strength from alloy precipitates in an austenitic or martensitic stainless steel matrix. To obtain weld properties neat those of the base metal, these steels are heat treated after welding. 

The body-centered-cuhic (bcc) metals and alloys are normally classified as undesirable for low temperature construction. This class includes Fe, the martensitic steels (low carbon and the 400-series stainless steels). Mo, and Nb. If not brittle at room temperature, these materials exhibit a ductile-to-brittle transition at low temperatures. Cold working of some steels, in particular, can induce the austenite-to-martensite transition. 

To make martensite in pure iron it has to be cooled very fast at about 10 °C s h Metals can only be cooled at such large rates if they are in the form of thin foils. How, then, can martensite be made in sizeable pieces of 0.8% carbon steel As we saw in the "Teaching Yourself Phase Diagrams" course, a 0.8% carbon steel is a "eutectoid" steel when it is cooled relatively slowly it transforms by diffusion into pearlite (the eutectoid mixture of a + FejC). The eutectoid reaction can only start when the steel has been cooled below 723°C. The nose of the C-curve occurs at = 525°C (Fig. 8.11), about 175°C lower than the nose temperature of perhaps 700°C for pure iron (Fig. 8.5). Diffusion is much slower at 525°C than it is at 700°C. As a result, a cooling rate of 200°C s misses the nose of the 1% curve and produces martensite. 

Martensite transformations are not limited just to metals. Some ceramics, like zirconia, have them and even the obscure system of (argon + 40 atom% nitrogen) forms martensite when it is cooled below 30 K. Helical protein crystals in some bacteria undergo a martensitic transformation and the shape change helps the bacteria to burrow into the skins of animals and people ... 

Many metals and metallic alloys show martensitic transformations at temperatures below the melting point. Martensitic transformations are structural phase changes of first order which belong to the broader class of diffusion js solid-state phase transformations. These are structural transformations of the crystal lattice, which do not involve long-range atomic movements. A recent review of the properties and the classification of diffusionless transformations has been given by Delayed... 

Martensitic traasfonnation Master ec[uations Mean field crossover to Ising Mechanical properties Metallic alloys Metallic glasses Metastable alloys Microhardness test Microscopic theory of nucleation... 

Cable-tool drilling lines. Movement of wire rope against metallic parts can accelerate wear. This can also create sufficient heat to form martensite, causing embrittlement of wire and early wire rope removal. Such also can be formed by friction against the casing or hard rock formation. 

Martensite is a hard, nonductile microconstituent formed when steel is heated above its critical temperature and cooled rapidly. In the case of steel of the composition conventionally used for rope wire, martensite can be formed if the wire surface is heated to a temperature near or somewhat in excess of 1400°F (760°C), and then cooled at a comparatively rapid rate. The presence of a martensite film at the surface of the outer wires of a rope that has been in service is evidence that sufficient frictional heat has been generated on the crown of the rope wires to momentarily raise the wire surface temperature to a point above the critical temperature range of the steel. The heated surface is then rapidly cooled by the adjacent cold metal within the wire and the rope structure, and an effective quenching results. 

Examples of martensitic transformation. This kind of transformation has been observed in a number of substances elements, compounds, alloys, minerals, metallic and ceramic materials. A few examples of systems showing a... 

Characteristics and implementation of the treatments depend on the expected results and on the properties of the material considered a variety of processes are employed. In ferrous alloys, in steels, a eutectoid transformation plays a prominent role, and aspects described by time-temperature-transformation diagrams and martensite formation are of relevant interest. See a short presentation of these points in 5.10.4.5. Titanium alloys are an example of the formation of structures in which two phases may be present in comparable quantities. A few remarks about a and (3 Ti alloys and the relevant heat treatments have been made in 5.6.4.1.1. More generally, for the various metals, the existence of different crystal forms, their transformation temperatures, and the extension of solid-solution ranges with other metals are preliminary points in the definition of convenient heat treatments and of their effects. In the evaluation and planning of the treatments, due consideration must be given to the heating and/or cooling rate and to the diffusion processes (in pure metals and in alloys). 

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