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Manifold dimension

Figure 1. Diagram of the apparatus used in the s3mthesis and isolation of V(CO)g. Components (A) round-bottom flask, 500 mL (B) connecting tube, (C) specially adapted Schlenk tube receiver (D) stopcock (E) Dewar flask (F) water bath (G) butyl rubber vacuum tubing connection to vacuum/argon manifold. Dimensions a =165 mm b = 130 mm c = 170 mm d = 75 mm e = 20mm od. Figure 1. Diagram of the apparatus used in the s3mthesis and isolation of V(CO)g. Components (A) round-bottom flask, 500 mL (B) connecting tube, (C) specially adapted Schlenk tube receiver (D) stopcock (E) Dewar flask (F) water bath (G) butyl rubber vacuum tubing connection to vacuum/argon manifold. Dimensions a =165 mm b = 130 mm c = 170 mm d = 75 mm e = 20mm od.
Horizontal pre.s.sure leaf filters. In these filters the leaves may be rectangular leaves which run parallel to the axis and are of varying sizes since they form chords of the shell or they may be circular or square elements parallel to the head of the shell, and aU of the same dimension. The leaves may be supported in the sheU from an independent rack, individuaUy from the shell, or from a filtrate manifold. Horizontal filters are particiilarly suited to diy-cake discharge. [Pg.1712]

In the previous section we saw on an example the main steps of a standard statistical mechanical description of an interface. First, we introduce a Hamiltonian describing the interaction between particles. In principle this Hamiltonian is known from the model introduced at a microscopic level. Then we calculate the free energy and the interfacial structure via some approximations. In principle, this approach requires us to explore the overall phase space which is a manifold of dimension 6N equal to the number of degrees of freedom for the total number of particles, N, in the system. [Pg.806]

As the physical scale of a reactor increases by numbering up more channels, the micromanifold challenge increases. Fluid distribution occurs in multiple dimensions within a layer [15, 16], from one layer to another [17], and from one reactor to another [18]. An external manifold, also known as the macromanifold or tube connection, as shown in Figure 11.2a, brings the fluids from inlet pipes to the many parallel layers in medium- to large-capacity reactors. [Pg.242]

This equation has been derived as a model amplitude equation in several contexts, from the flow of thin fluid films down an inclined plane to the development of instabilities on flame fronts and pattern formation in reaction-diffusion systems we will not discuss here the validity of the K-S as a model of the above physicochemical processes (see (5) and references therein). Extensive theoretical and numerical work on several versions of the K-S has been performed by many researchers (2). One of the main reasons is the rich patterns of dynamic behavior and transitions that this model exhibits even in one spatial dimension. This makes it a testing ground for methods and algorithms for the study and analysis of complex dynamics. Another reason is the recent theory of Inertial Manifolds, through which it can be shown that the K-S is strictly equivalent to a low dimensional dynamical system (a set of Ordinary Differentia Equations) (6). The dimension of this set of course varies as the parameter a varies. This implies that the various bifurcations of the solutions of the K-S as well as the chaotic dynamics associated with them can be predicted by low-dimensional sets of ODEs. It is interesting that the Inertial Manifold Theory provides an algorithmic approach for the construction of this set of ODEs. [Pg.285]

The point q = p = 0 (or P = Q = 0) is a fixed point of the dynamics in the reactive mode. In the full-dimensional dynamics, it corresponds to all trajectories in which only the motion in the bath modes is excited. These trajectories are characterized by the property that they remain confined to the neighborhood of the saddle point for all time. They correspond to a bound state in the continuum, and thus to the transition state in the sense of Ref. 20. Because it is described by the two independent conditions q = 0 and p = 0, the set of all initial conditions that give rise to trajectories in the transition state forms a manifold of dimension 2/V — 2 in the full 2/V-dimensional phase space. It is called the central manifold of the saddle point. The central manifold is subdivided into level sets of the Hamiltonian in Eq. (5), each of which has dimension 2N — 1. These energy shells are normally hyperbolic invariant manifolds (NHIM) of the dynamical system [88]. Following Ref. 34, we use the term NHIM to refer to these objects. In the special case of the two-dimensional system, every NHIM has dimension one. It reduces to a periodic orbit and reproduces the well-known PODS [20-22]. [Pg.198]

This is exactly the autonomous linearized Hamiltonian (7), the dynamics of which was discussed in detail in Section II. One therefore finds the TS dividing surface and the full set of invariant manifolds described earlier one-dimensional stable and unstable manifolds corresponding to the dynamics of the variables A<2i and APt, respectively, and a central manifold of dimension 2N — 2 that itself decomposes into two-dimensional invariant subspaces spanned by APj and AQj. However, all these manifolds are now moving manifolds that are attached to the TS trajectory. Their actual location in phase space at any given time is obtained from their description in terms of relative coordinates by the time-dependent shift of origin, Eq. (42). [Pg.223]

It is possible, however, to avoid any violation of these fundamental properties, and derive a result on the local electron densities of non-zero volume subsystems of boundaryless electron densities of complete molecules [159-161]. A four-dimensional representation of molecular electron densities is constructed by taking the first three dimensions as those corresponding to the ordinary three-space E3 and the fourth dimension as that representing the electron density values p(r). Using a compactifi-cation method, all points of the ordinary three- dimensional space E3 can be mapped to a manifold S3 embedded in a four- dimensional Euclidean space E4, where the addition of a single point leads to a compact manifold representation of the entire, boundaryless molecular electron density. [Pg.67]

Several methods have been developed to determine the chemical shift anisotropies in the presence of small and large quadrupolar broadenings, including lineshape analysis of CT or CT plus ST spectra measured under static, MAS, or high-resolution conditions [206-210]. These methods allow for determination of the quadrupolar parameters (Cq, i)q) and chemical shift parameters (dcs, //cs> <5CT), as well as the relative orientation of the quadrupolar and chemical shift tensors. In this context, the MQMAS experiment can be useful, as it scales the CSA by a factor of p in the isotropic dimension, allowing for determination of chemical shift parameters from the spinning sideband manifold [211],... [Pg.164]

Let X be a smooth projective variety of dimension d over an algebraically closed field k. In this section we want to define a variety D (X) of second order data of m-dimensional subvarieties of X for any non-negative integer m < d. A general point of D ln X) will correspond to the second order datum of the germ of a smooth m-dimensional subvariety Y C X in a point x X, i.e. to the quotient of Ox,x- Assume for the moment that the ground field is C and x Y C X, X is a smooth complex d-manifold and we have local coordinates zi,..., at x. Then Y is given by equations... [Pg.82]

An example of a smart tabulation method is the intrinsic, low-dimensional manifold (ILDM) approach (Maas and Pope 1992). This method attempts to reduce the number of dimensions that must be tabulated by projecting the composition vectors onto the nonlinear manifold defined by the slowest chemical time scales.162 In combusting systems far from extinction, the number of slow chemical time scales is typically very small (i.e, one to three). Thus the resulting non-linear slow manifold ILDM will be low-dimensional (see Fig. 6.7), and can be accurately tabulated. However, because the ILDM is non-linear, it is usually difficult to find and to parameterize for a detailed kinetic scheme (especially if the number of slow dimensions is greater than three ). In addition, the shape, location in composition space, and dimension of the ILDM will depend on the inlet flow conditions (i.e., temperature, pressure, species concentrations, etc.). Since the time and computational effort required to construct an ILDM is relatively large, the ILDM approach has yet to find widespread use in transported PDF simulations outside combustion. [Pg.331]

Note that the dimensions of the fast and slow manifolds will depend upon the time step. In the limit where At is much larger than all chemical time scales, the slow manifold will be zero-dimensional. Note also that the fast and slow manifolds are defined locally in composition space. Hence, depending on the location of 0q], the dimensions of the slow manifold can vary greatly. In contrast to the ILDM method, wherein the dimension of the slow manifold must be globally constant (and less than two or three ), ISAT is applicable to slow manifolds of any dimension. Naturally this flexibility comes with a cost ISAT does not reduce the number (Ns) of scalars that are needed to describe a reacting flow.168... [Pg.334]

The price which must be paid in order to make the action local is that the spatial dimension must be augmented by one. Hence, the integral must be performed over a five-dimensional manifold whose boundary (M4) is ordinary Minkowski space. In [27, 32, 36] the constant C has been shown to be the... [Pg.152]

Let Ml, M2 be oriented smooth (possibly non-compact) manifolds of dimensions di, 2 respectively. Take a submanifold Z in Mi x M2 such that... [Pg.82]

A. Fujiki, On primitive symplectic compact Kahler V-manifolds of dimension four, in Classification of Algebraic and Analytic Manifolds , K.Ueno (ed.). Progress in Mathematics, Birkhauser 39 (1983), 71-125. [Pg.113]

Figure 6-1. In addition to the site description, there is a statement of all the conditions being monitored, the m ods used, and the numerical specifications for the sampling probe, both for the sampling manifold and for the connections from the manifold to the instruments. A third page (not included here) shows a schematic drawing with the dimensions and locations of the bends in the ducting. The sampling-probe specifications currently in effect at four major air pollution control agencies are summarized in Table 6-4. Figure 6-1. In addition to the site description, there is a statement of all the conditions being monitored, the m ods used, and the numerical specifications for the sampling probe, both for the sampling manifold and for the connections from the manifold to the instruments. A third page (not included here) shows a schematic drawing with the dimensions and locations of the bends in the ducting. The sampling-probe specifications currently in effect at four major air pollution control agencies are summarized in Table 6-4.
In the previous equation, the sum runs over all critical points of the gradient dynamical system. In the Bonding Evolution Theory, the critical points form the molecular graph. In this graph, they are represented according to the dimension of their unstable manifold. Thus, critical points of / = 0, are associated with a dot, these with I = 1 are associated with a line, these with / = 2 by faces, and finally these with 7=3 by 3D cages. [Pg.357]

The corresponding structure of fast-slow time separation in phase space is not necessarily a smooth slow invariant manifold, but may be similar to a "crazy quilt" and may consist of fragments of various dimensions that do not join smoothly or even continuously. [Pg.166]

String theory may be more appropriate to departments of mathematics or even schools of divinity. How many angels can dance on the head of a pin How many dimensions are there in a compacted manifold thirty powers of ten smaller than a pinhead Will all the young Ph.D.s, after wasting years on string theory, be employable when the string snaps ... [Pg.14]


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See also in sourсe #XX -- [ Pg.260 ]




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