Magnetic field pulse schemes

FIGURE 8.9 Magnetic field pulse schemes used in the measurement of g-pair lifetime and the separation of g- and f-pair RP kinetics. 

A much simpler and more flexible approach, however, extends the scheme of pulsed magnetic field gradients discussed above to include more complex time dependences. To see how this can be done, we write down the general dependence of the phase shift accumulated at time t subject to a space-dependent Larmor frequency ... 

Fig. 10.4 Experimental scheme for the 2D [ N. HJ-TROSY using single transition to single transition polarization transfer (box labeled ST2-PT). On the lines marked H and 15N, narrow and wide bars stand for nonselective 90° and 180° radio-frequency pulses, respectively. The delay t=2.7 ms (see text). The line marked PFG indicates the pulsed magnetic field gradients applied along the z-axis G, amplitude 30 G/cm, duration 1 ms G2, 40 G/cm, 1 ms G3, 40 G/cm, 1 ms ...

Figure 12.4 The pulse scheme of the three-pulse echo sequence to determine Xe diffusion coefficients in polymers and other porous systems. The shaded areas are magnetic field gradient pulses with amplitude g and length 8. The time between the two gradient pulses A determines the time during which the diffusion path length is...

Properly designed hardware is important to any successful detection scheme. At first glance, the NQR hardware requirements are deceptively simple a device to generate a strong RF magnetic field and another to detect a weak RF magnetic field. Clearly, there are parallels between these requirements and those of pulsed radar, and some early NMR systems were built around surplus radar hardware. In this section, NQR hardware and how it affects detection sensitivity is discussed. 

In the following, we show how an MQMAS echo is formed. The quadmpolar Hamiltonian under MAS will be derived as a perturbation to the strong static magnetic field Bq. The evolution of the density matrix under this Hamiltonian will be then shown to form an echo under a suitable selection of symmetric coherences. The manipulation of spin coherences by RF pulses will be assumed to be ideal here. The effects of nonidealities were discussed by the group of Vega. From the expression for the elements of the quadmpolar Hamiltonian, line narrowing by DOR experiment and echo formation by two alternative experiments, DAS and STMAS, will also be demonstrated and briefly discussed. Finally, some additional line narrowing schemes will be mentioned. 

Fig. 1.33. Setup used by Smalley and coworkers to inject cluster ions into an ICR cell. The cluster beam is steered and focused by deflection plates and two Einzel lenses. Before entering the ICR cell, the cluster ions are decelerated. The inset shows the principle of an ICR mass spectrometer. Ions are excited by an rf-pulse to propagate in circular orbits. The image currents induced in the electrode plates are amplified and analyzed through computer-based Fourier transformation. The magnetic field in this scheme is perpendicular to the drawing plane. The schemes have been adopted from [71,177,178]...

---