Magnesium compounds synthesis

Gngnard reagents - [BROMINE COMPOUNDS] (Vol 4) - [ESTERS, ORGANIC] (Vol 9) -from benzene [BENZENE] (Vol 4) -chemiluminescence [LUMINESCENTMATERIALS - CHEMILUMINESCENCE] (Vol 15) -magnesium alkyls from [MAGNESIUM COMPOUNDS] (Vol 15) -reaction of propylene oxides [PROPYLENE OXIDE] (Vol 20) -for silanes [SILICON COMPOUNDS - SILANES] (Vol 22) -for sulfoxide synthesis [SULFOXIDES] (Vol 23)... 

A general method for the synthesis of organomercurials is the transmetallation of mercury(n) salts with other organometalhc species. Organohthium and -magnesium compounds continue to be widely employed for the preparation of complexes with formula RHgX or HgR2 (see equation 1). 

Synthesis of dienes [1, 169, before references], Tetrahydrofurane solutions of vinylmagnesium halides are readily accessible from vinyl halides by the method of Normant.19 Kauffmann and Sahm20 found that when a THF solution of the vinyl-magnesium compound (1) is treated at —60° to —40° under nitrogen with a suspension of cuprous chloride an intensely green or red solution is obtained which presumably contains a vinylcopper compound. When the mixture is warmed to... 

Where they are known, the organic compounds of Ca, Sr and Ba are highly ionic, reactive, and of little utility or importance. Magnesium compounds, of which the Grignard reagents are the best known, are probably the most widely used of all organometallic compounds. They are employed for the synthesis of alkyl and aryl compounds of other elements as well as for a host of organic syntheses. 

For the synthesis of a number of magnesium compounds, such as magnesium stearate, used in specialized types of soaps. 

The main methods of synthesis of cyclopentadienyltrinickel clusters are the reactions of nickelocene with organolithium or -magnesium compounds (Eq. (1))... 

Magnesium amalgam Terminal ethylene derivatives from 0X0 compounds Synthesis with addition of 1 C-atom... 

Bogdanovic, B. (1985) Catalytic synthesis of organolithium and magnesium compounds and of lithium and magnesium hydrides. Angew. Chem. Int. Edn), 24, 262. 

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