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M-Aminoanisole

It had been known many years earlier that aromatic nucleophilic substitution occasionally results in substitution at a different position. This is called cine substitution and can be illustrated by the conversion of o-bromoanisole to m-aminoanisole. In this particular case, only the meta isomer is formed. The... [Pg.854]

In each case the predicted product was the one chiefly formed.57 The obtention of m-aminoanisole, mentioned on p. 647, is also in accord with these predictions. [Pg.652]

According to Roberts et the direction of addition of ammonia to 3-substituted benzynes might be predicted by considering the amide ion to add so as to provide the most favorable location of the negative charge with respect to the inductive effect of the orienting substituent. Thus, ammonia adds to 3-methoxybenzyne (39) producing chiefly m-aminoanisole (40). [Pg.130]

Beilstein Handbook Reference) AI3-52519 1-Amino-3-methoxybenzene 3-Aminoanisole m-Aminoanisole 3-Anisidine m-Anisidine m-Anisylamine Benzenamine, 3-methoxy- Benzenamine, 3-methoxy- BRN 0386119 CCRIS 5886 EINECS 208-6514 m-Methoxyaniline 3-Methoxyaniline 3-Methoxy-benzenamine NSC 7631. Chemical Intermediate. Liquid mp = -1° bp = 251° d = 1.0960 km = 285 nm (cyclohexane) slightly soluble in H2O, CCI4, soluble in EtOH, EtzO, MezCO, CeHe. Penta Mfg. Rhdne-Poulenc Sigma-Aldrich Fine Chem. [Pg.40]

Aminoanisole. See p-Anisidine m-Aminoanisole. See m-Anisidine o-Aminoanisole. See o-Anisidine p-Aminoanisole. See p-Anisidine 2-Aminoanisole hydrochloride. See o-Anisidine... [Pg.211]

Synonyms 3-Aminoanisole m-Aminoanisole m-Anisylamine Benzenamine, 3-methoxy- 3-Methoxyaniline... [Pg.312]

Synonyms AI3-08584 2-Aminoanisole o-Aminoanisole l-Amino-2-methoxybenzene 2-Anis-idine 2-Anisylamine o-Anisylamine BRN 0386210 CCRIS 768 EINECS 201-963-1 2-Methoxy-l-aminobenzene 2-Methoxyaniline o-M ethoxy aniline 2-Methoxybenzenamine o-Methoxyphenylamine NSC 3122 UN 2431. [Pg.109]

The 3-nitro-4-aminoanisole was the technical commercial product, m.p. 124-126°, obtained from E. I. du Pont de Nemours and Company. [Pg.50]

SYNS m-AMINO-p-CRESOL, METHYL ESTER 3-AMINO-p-CRESOL METHYL ESTER l-AMINO-2-METHOXY-5-METHYLBENZENE 3-AMINO-4-METHOXYTOLUENE 2-AMINO-4-METHYLANISOLE AZOIC RED 36 C.I, AZOIC RED 83 CRESIDINE p-CRESIDINE KRESIDIN KREZIDINE 2-METHOXY-5-METHYLANILINE 2-METHOXY-5-METHYL-BENZENAMINE (9CI) 4-METHOXY-m-TOLUIDINE 4-METHYL-2-AMINOANISOLE NCI-C02982... [Pg.900]

AMINOANILINE DIHYDROCHLORIDE see PEY750 m-AMINOANILINE DIHYDROCHLORIDE see PEY750 2-AMINOANISOLE see AOV900... [Pg.1505]

Other functional groups may be present during reduction. Aromatic amino ethers are prepared by the same general procedures described above, e.g., 772-aminoanisole (80%) and 2-aminodiphenyl ether (94%). The reduction of o-nitrobenzaldehyde to the sensitive o-aminobenzaldehyde is successfully accomplished by the action of ferrous sulfate and ammonia (75%). m-Dimethylaminobenzaldehyde is formed by reduction of the nitro acetal in aqueous solution with sodium sulfide followed by methyla-tion (74% over-all) or by catalytic reduction of m-nitrobenzaldehyde in... [Pg.333]

Methoxy-5-methylaniline 2-Methoxy-5-methylbenzenamine 4-Methoxy-m-toluidine 4-Methyl-2-aminoanisole 5-Methyl-o-anisidine... [Pg.1081]

S>Broix),o-m-axiisidijie (B-Bromo-m-arntno phmdl methyl ether, 5d>romo-2-aminoanisole)... [Pg.277]

Me ether dimethyl-p-anisidine, 4-dimethyl-aminoanisole. Leaflets from EtOH. M.p. 49°. [Pg.895]

DATE can be prepared by nitrating m-dichlorobenzene to 2,4,6-trinitro-1,3dichlorobenzene and aminating in methanol solutions. Another method of preparation is by the amination of 2,4,6-trinitro-3-aminoanisole. In a third method of preparation phosphorous oxytrichloride and dipyridinium styphnate are reacted directly at steam bath temperature and a suspension of the resulting 2,4,6-trinitrol, 3-dichlorobenzene in methanol is treated with gaseous ammonia. Impact sensitivity is 200 percent that of TNT. Table 8-37 shows the gap test results for DATE. [Pg.148]

See other pages where M-Aminoanisole is mentioned: [Pg.647]    [Pg.196]    [Pg.130]    [Pg.107]    [Pg.108]    [Pg.803]    [Pg.130]    [Pg.196]    [Pg.167]    [Pg.103]    [Pg.73]    [Pg.647]    [Pg.196]    [Pg.130]    [Pg.107]    [Pg.108]    [Pg.803]    [Pg.130]    [Pg.196]    [Pg.167]    [Pg.103]    [Pg.73]    [Pg.130]    [Pg.196]    [Pg.40]    [Pg.306]    [Pg.196]    [Pg.211]    [Pg.314]    [Pg.895]    [Pg.204]    [Pg.969]    [Pg.969]   


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