Lithium-vanadium oxide secondary batteries

Table 11. Specifications of secondary lithium-vanadium oxide batteries...

Secondary lithium-metal batteries which have a lithium-metal anode are attractive because their energy density is theoretically higher than that of lithium-ion batteries. Lithium-molybdenum disulfide batteries were the world s first secondary cylindrical lithium—metal batteries. However, the batteries were recalled in 1989 because of an overheating defect. Lithium-manganese dioxide batteries are the only secondary cylindrical lithium—metal batteries which are manufactured at present. Lithium-vanadium oxide batteries are being researched and developed. Furthermore, electrolytes, electrolyte additives and lithium surface treatments are being studied to improve safety and recharge-ability. 

Lithium-Vanadium Oxide 2.5.3 Lithium-Polyaniline Secondary Batteries Batteries... 

Catalogue of lithium-vanadium oxide secondary batteries, Matsushita Battery Industrial Co., Ltd., 1996. 

Sakamoto, J.S. and B. Dunn. 2002. Vanadium oxide-carbon nanotube composite electrodes for use in secondary lithium batteries. J. Electrochem. Soc. 149 A26-A30. 

Sakamoto JS, Dunn B (2002) Vanadium oxide-carbon nanotube composite electrodes for use in secondary lithium batteries. J Electrochem Soc 149(1) A26-A30. doi 10.1149/l.1425791 Bresser D, Paillard E, Copley M, Bishop P, Winter M, Passerini S (2012) The importance of going nano for high power battery materials. J Power Sources 219 217-222. doi 10.1016/j. jpowsour.2012.07.035... 

In addition to vanadates, molybdenum oxides should also attract an attention as anode material for Li-ion rechargeable battery because they also have various oxidation states like vanadium. Related molybdenum compounds, Aubom et al. [5] have proposed molybdenum oxide MoOg as anode material for lithium secondary battery more than ten years ago. However, their study was limited by experimental conditions such as poor stability of the electrolyte at low potential. Here, we prepared M11M0O4 using sohd-state reaction [7,8]. 

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