Cerium chloride lithium aluminum hydride

Diphenylphosphine)lithium, 126 Nickel boride, 197 Samarium(II) iodide, 270 to 1,2-disubstituted compounds B-3-Pinanyl-9-borabicyclo-[3.3.1]nonane, 249 Titanium(III) chloride, 302 of phosphorus compounds Lithium aluminum hydride-Cerium(III) chloride, 159 of sulfoxides and sulfones Sodium iodide-Boron trifluoride ether-ate, 282... [Pg.372]

Lithium aluminum hydride, 61, 62, 282 Lithium aluminum hydride-Bis-(cyclopentadienyl)nickel, 158 Lithium aluminum hydride-Cerium(III) chloride, 159 Lithium aluminum hydride-Hexa-methylphosphoric triamide, 159 Lithium aluminum hydride-Potassium methoxide, 159... [Pg.406]

Related Reagents. Lithium Aluminum Hydride-(2,2 -Bipy-ridyl)(l,5-cyclooctadiene)nickel Lithium Aluminum Hydride-Bis(cyclopentadienyl)nickel Lithium Aluminum Hydride-Boron Trifluoride Etherate Lithium Aluminum Hydride-Cerium(III) Chloride Lithium Aluminum Hydride-2,2 -Dihydroxy-l, E-binaphthyl Lithium Aluminum Hydride-Chromium(III) Chloride Lithium Aluminum Hydride-Cobalt(II) Chloride Lithium Aluminum Hydride-Copper(I) Iodide Lithium Aluminum Hydride-Diphosphoms Tetraiodide Lithium Aluminum Hydride-Nickel(II) Chloride Lithium Aluminum Hydride-Titanium(IV) Chloride Titanium(III) Chloride-Lithium Aluminum Hydride. [Pg.215]

Both 1- and 2-fluoronaphthalenes are reduced to naphthalene by a mixture of hydrazine and its sodium salt, in 39 and 60% yield, respectively.63 As in the case of other monofluoroarenes, more efficient reduction is achieved by lithium aluminum hydride combined with cerium(III) chloride in refluxing tetrahydrofuran.1011 1,2,3,4-Tetrafluoronaphthalene (6) is monoreduced by lithium aluminum hydride at C2 with complete regioselcctivity to give trifluoronaphthalene... [Pg.316]

HOMOALLYLIC ALCOHOLS Cerium amalgam. Chromium(II) chloride. Fluorodimethoxyborane. Hypochlorous acid. Lithium bronze. Manganesc(II) chloride-Lithium aluminum hydride. Methylenetriphenylphosphorane. Organotitanium reagents. Tetrakis(triphenylphosphine)palladium. Tin. Tin(II) fluoride. [Pg.313]

Sodium borohydride and potassium borohydride react regioselectively with the formyl group of alkyl 2-formylcyclopropanecarboxylates lithium aluminum hydride is unseleetive. Stereospecific reduction of the formyl group was observed when formyl-cyclo-propanes were subjected to yeast alcohol dehydrogenase. ei Furthermore, regiospecific reduction of the aldehyde function in a 2-cyclopropylprop-2-enal derivative was performed using a mixture of sodium borohydride and cerium(III) chloride. [Pg.1729]

Related Reagents. See entries for other Lewis Acids, e.g. Zinc Chloride, Aluminum Chloride, 1Uanium(IV) Chloride-, also see entries for Boron Trifluoride (and combination reagents), and combination reagents employing Boron Trifluoride Etherate, e.g. ButyUithium—Boron Trifluoride herate, Cerium(III) Acetate-Boron Trifluoride Etherate, Lithium Aluminum Hydride-Boron Trifluoride Etherate, Methylcopper-Boron Trifluoride Etherate,... [Pg.39]