Layer susceptibility

The various influences on stratospheric ozone caused by trace gases having their origin in the troposphere make the ozone layer susceptible to considerable perturbations, both natural and human. Currently of greatest interest are the effects of the chlorofluorocarbons, but there are others as well, such as variations in the mixing ratios of N20 and methane in the troposphere, or the rise of C02 in the atmosphere. The last constituent does not enter into chemical reactions, but it cools the stratosphere, thereby lowering the rates of important reactions such as that of OH with HCI. The various... 

To illustrate these effects, we show in fig. 31 a schematic representation of the diffuse scattering around the (110) point in UAs at 7 -1- 1.2K (Sinha etal. 1981) Along the [001] direction q is parallel to the propagation direction and the moment component in the ordered state, so that this probes X (Q)- We see that the scattering width is wide, so is correspondingly small. Conversely, in the [ < 0] direction we probe Xi(Q)> Ihe inter-layer susceptibility, as discussed earlier, and the widths are quite sharp, leading to a large value of. These values of can be measured as a function of temperature (we shall discuss this below), but their ratio is found to be... 

Corrosion Control. Sihca in water exposed to various metals leads to the formation of a surface less susceptible to corrosion. A likely explanation is the formation of metahosihcate complexes at the metal—water interface after an initial dismption of the metal oxide layer and formation of an active site. This modified surface is expected to be more resistant to subsequent corrosive action via lowered surface activity or reduced diffusion. 

ActivatedL yer Loss. Loss of the catalytic layer is the third method of deactivation. Attrition, erosion, or loss of adhesion and exfoHation of the active catalytic layer aU. result in loss of catalyst performance. The monolithic honeycomb catalyst is designed to be resistant to aU. of these mechanisms. There is some erosion of the inlet edge of the cells at the entrance to the monolithic honeycomb, but this loss is minor. The peUetted catalyst is more susceptible to attrition losses because the pellets in the catalytic bed mb against each other. Improvements in the design of the peUetted converter, the surface hardness of the peUets, and the depth of the active layer of the peUets also minimise loss of catalyst performance from attrition in that converter. 

Metals that produce protective oxide layers (such as stainless steels) are especially susceptible to crevice attack. The reduced oxygen concentration in the crevice inhibits repair of the protective oxide film. This is especially true if acidic anions are present, which further retards oxide repair. Stainless steels containing molybdenum are usually less susceptible to attack. 

Zinc is susceptible to attack from oiQ gen concentration cells. Shielded areas or areas depleted in oxygen concentration tend to corrode, forming voluminous, white, friable corrosion products. Once the zinc layer is breached, the underlying steel becomes susceptible to attack and is severely wasted locally (Figs. 5.12 and 5.13). 

Alloys whose corrosion resistance depends on forming a protective oxide layer, such as stainless steel, are susceptible to severe localized attack when pH falls as a result of nonoxidizing acid excursions. How-... 

The aluminum alloys most commonly bonded are 2024 bare, 2024 clad and 7075 bare. Clad 7075 was also used extensively in early bonded structure but was largely abandoned after service performance demonstrated that it was susceptible to rapid dissolution or corrosion of the clad layer. Naturally aged tempers such as T3, in particular 2024-T3 because of its widespread use, are restricted to bonding with adhesives that cure at 250°F or below in order to avoid adversely affecting the temper. Various other alloys and tempers are bonded to a lesser extent, though the dominance of 7075 and 2024 is decreasing as higher-performance alloys and tempers are adopted. 

Items of plant fabricated from stainless steels should be inspected before first use and after any maintenance work or unplanned shutdown. All materials that rely for their corrosion resistance on the presence of an oxide or similar passive layer are susceptible to localized attack where that layer is absent or damaged. Damage is most commonly caused by scratching, metallic contamination (nearby grinding or touching with ferrous tools), embedding of grit and weld spatter. 

The presence of tensile stress in a metal surface renders that surface more susceptible to many kinds of corrosion than the same material in a non-stressed condition. Similarly, the presence of compressive stress in the surface layer can be beneficial for corrosion behavior. 

Shot peening is a beneficial surface treatment since it puts the surface into a state of compression and generally obscures the grain structure. Subsequent painting of the peened surface is often useful. If pitting occurs then cracking can be expected in susceptible material when the attack penetrates the depth of the compressed surface layer. 

Figures 12-12 and 12-13 document that trap-free SCL-conduction can, in fact, also be observed in the case of electron transport. Data in Figure 12-12 were obtained for a single layer of polystyrene with a CF -substituted vinylquateiphenyl chain copolymer, sandwiched between an ITO anode and a calcium cathode and given that oxidation and reduction potentials of the material majority curriers can only be electrons. Data analysis in terms of Eq. (12.5) yields an electron mobility of 8xl0 ycm2 V 1 s . The rather low value is due to the dilution of the charge carrying moiety. The obvious reason why in this case no trap-limited SCL conduction is observed is that the ClVquatciphenyl. substituent is not susceptible to chemical oxidation.

Hurst (19) discusses the similarity in action of the pyrethrins and of DDT as indicated by a dispersant action on the lipids of insect cuticle and internal tissue. He has developed an elaborate theory of contact insecticidal action but provides no experimental data. Hurst believes that the susceptibility to insecticides depends partially on the cuticular permeability, but more fundamentally on the effects on internal tissue receptors which control oxidative metabolism or oxidative enzyme systems. The access of pyrethrins to insects, for example, is facilitated by adsorption and storage in the lipophilic layers of the epicuticle. The epicuticle is to be regarded as a lipoprotein mosaic consisting of alternating patches of lipid and protein receptors which are sites of oxidase activity. Such a condition exists in both the hydrophilic type of cuticle found in larvae of Calliphora and Phormia and in the waxy cuticle of Tenebrio larvae. Hurst explains pyrethrinization as a preliminary narcosis or knockdown phase in which oxidase action is blocked by adsorption of the insecticide on the lipoprotein tissue components, followed by death when further dispersant action of the insecticide results in an irreversible increase in the phenoloxidase activity as a result of the displacement of protective lipids. This increase in phenoloxidase activity is accompanied by the accumulation of toxic quinoid metabolites in the blood and tissues—for example, O-quinones which would block substrate access to normal enzyme systems. The varying degrees of susceptibility shown by different insect species to an insecticide may be explainable not only in terms of differences in cuticle make-up but also as internal factors associated with the stability of oxidase systems. 

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