Laser induced fluorescence modulated population

This optical-optical double-resonance technique has already been used for other Doppler-free techniques [10.25], such as polarization spectroscopy (see Sect.10.3). Its applications to molecular beams has, however, the following advantages compared to spectroscopy in gas cells. When the chopped pump laser periodically depletes the level E. and populates level Ej, there are two relaxation mechanisms in gas cells which may transfer the population modulation to other levels. These are collision processes and laser-induced fluorescence (see Fig.8.39). The neighboring levels therefore also show a modulation and the modulated excitation spectrum induced by the probe laser includes all lines which are excited from those levels. If several absorption lines overlap within their Doppler width, the pump laser simultaneously excites several upper states and also partly depletes several lower levels. 

The quantity measured in such experiments is the relative modulation of the probe laser-induced fluorescence intensity Ip-j which reflects the modulation of the lower level population N... 

---