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Kinetics according to Borchardt and Daniels

Experiments on model substances were not carried out. A comparison of the oxidation and pyrolysis kinetics according to Borchardt and Daniels with the other three methods will be made in chapter 4.10. [Pg.89]

CflNVEHIION 10 M 1 RXN OROeN 1 ] relatlv actxvatxon SNeMV ( HJ/nela ) PRB-EXPaNBNTlAL FACTOR (1/mln) Convers1on absolute 1.23 2 fa.84446 B.071BaE+ll  [Pg.92]

CONVaROION SO S C RXN OROBR 1 ] ACTIVATION EMEROY ( KJ/fflOl ) PRE-KXPONBNTIAL FACTOR tl/min) B8.3BB33 I.STBBIAE+IO 2.46 S [Pg.92]

OONVERXIONl BO X C RXN ORCBR 1 1 ACTIVATION SN6R0Y ( KJ/nelB ) FRE-BXPONENTIAL FACTOR (1/mln) 71.S8BBB a.QB4134B reB 7.38 % [Pg.92]

CONVERBIONt 70 X I RXN ORCBR 1 ] AOriVATION ENBROY ( kJ/molm ) RM-CXPON8NTXA1. FACTOR (1/Rln) B7.S34B3 B.669S8BB407 8.61 % [Pg.92]

Software only for the Simultaneous Thermal Analyzer STA 780 was available for kinetics according to Borchardt and Daniels. Similarly to the kinetics program according to ASTM E 698-79, only separately sampled DTA data can be processed using the Borchardt and Daniels program. The DTA data from simultaneous TGA/DTA experiments cannot be... [Pg.440]

The application of thermoanalytical methods to the investigation of the kinetics of pyrolysis and oxidation processes of heavy petroleum components representing multi-component systems proved to be successful. Whereas the ASTM E 698-79 and the Flynn and Wall methods can be applied relatively uncritically, the interpretation of the data from the McCarty and Green method requires a solid knowledge of the thermal and oxidative behavior of the samples. The attempt to use the evaluation according to Borchardt and Daniels proved not to be successful for pyrolysis nor for oxidation reactions. Most of the... [Pg.482]

Kinetic analyses were performed on the initial reaction peaks for the uncured epoxy systems according to the method of Borchardt and Daniels (13). The calculated kinetic parameters are shown in Table 1. When BF MEA is added to the uncatalyzed system, the reaction order increases and the activation energy and... [Pg.8]

See other pages where Kinetics according to Borchardt and Daniels is mentioned: [Pg.71]    [Pg.89]    [Pg.440]    [Pg.468]    [Pg.71]    [Pg.89]    [Pg.440]    [Pg.468]    [Pg.453]    [Pg.468]    [Pg.478]   


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Daniell

Daniells

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