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Key Facts about the History of Structural and Functional Studies on ThDP-dependent Enzymes... [Pg.96]

Key Facts about the National Institute of Standards and Technology... [Pg.359]

The approach presented above is referred to as the empirical valence bond (EVB) method (Ref. 6). This approach exploits the simple physical picture of the VB model which allows for a convenient representation of the diagonal matrix elements by classical force fields and convenient incorporation of realistic solvent models in the solute Hamiltonian. A key point about the EVB method is its unique calibration using well-defined experimental information. That is, after evaluating the free-energy surface with the initial parameter a , we can use conveniently the fact that the free energy of the proton transfer reaction is given by... [Pg.58]

The key recognitive skill required to carry out the above tasks is the formation of a mental model of the process operations that fits the current facts about the process and enables the operators to correctly assess process behavior and predict the effects of possible control actions. Correct mental models of process operations have allowed operators to overcome the weakness of lost sensors and conflicting trends, even under the pressure of an emergency (Dvorak, 1987), whereas most of the operational mishandlings are due to an erroneous perception as to what is going on in the process (O Shima, 1983). [Pg.208]

Effective communication is a key element of emergency response, and a media or communications plan is essential to good communications. Be prepared by organizing basic facts about the crisis and your chemical system. Develop key messages to use with the media that are clear, brief, and accurate. Make sure your messages are carefully planned and have been coordinated with local and state officials. Considerations should be given to establishing protocols for both field and office staff to respectfully defer questions to the proper spokesperson. [Pg.142]

The key facts about competitive and cooperative planar systems are summarized next in terms of the Poincare map P for (4.1). [Pg.170]

U.S. Centers for Disease Control and Prevention (CDC), 2007. Key Facts about Influenza and the Influenza Vaccine Fact Sheet, available at http //www.cdc.gov/flu/keyfacts. htm (accessed September 3, 2007). [Pg.28]

To explain such facts, Linus Pauling proposed that the valence atomic orbitals in the molecule are different from those in the isolated atoms. Indeed, quantum-mechanical calculations show that if we mix specific combinations of orbitals mathematically, we obtain new atomic orbitals. The spatial orientations of these new orbitals lead to more stable bonds and are consistent with observed molecular shapes. The process of orbital mixing is called hybridization, and the new atomic orbitals are called hybrid orbitals. Two key points about the number and type of hybrid orbitals are that... [Pg.325]

One of the key facts about etale morphisms is Hensel s lemma, of which here is a variant ... [Pg.177]

The mathematics of enzyme kinetics can certainly look challenging. In fact, an understanding of kinetic parameters can often provide key information about the role of an enzyme within a living organism. Many of the ways of doing kinetic plots of this sort were developed by physical organic chemists, who then went on to propose mechanisms for reactions of aU sorts based on kinetic data (see Section 7.6). Four aspects are useful comparison of Kf, comparison of or turnover number, comparison of... [Pg.160]

Preparation may be understood as two fold. First, it is knowledge acquisition about the problem and the preparation of key facts for the session s participants. Second, it is the preparation of the participants and of the physical environment where the session will take place. [Pg.201]

In fact, as long as we have obtained a polymer sample, we need first to determine its basic physical properties. The determination mainly relies on the key information about the chemical details of that sample. In other words, we need to carry out the necessary characterization of the chemical structures of polymer chains. Here rises a question, what are the essential factors characterizing the chemical structures of polymer chains, from which we can make a proper speculation on the fundamental physical properties ... [Pg.14]

Another chemical concept worthy of sustained attention is that of a reaction mechanism. To the extent that chemistry is the science of the transformation of substances, a claim repeated often in this volume, the reaction mechanism becomes a primary tool for the explanation and prediction of key facts about complex reactions the nature of the various products, the quantities in which they are produced, and how these vary as the physical conditions change. In Chapter 4.2 Mechanisms and Chemical Reaction , William Goodwin argues that organic chemistry actually employs two related conceptions of mechanism, the thick and the thin . The thin conception of mechanism is entrenched in practice, and litters chemical laboratory blackboards, because according to Goodwin, it can reliably support inferences required to meet the particular predictive and explanatory aims of organic chemistry. Nevertheless, the thick conception of reaction mechanism is the one that most readily connects mathematical models of chemical transformation to the experimental facts measured in the laboratory. [Pg.11]

Once the broad outlines of DNA replication and protein biosynthesis were established scien tists speculated about how these outlines af fected various origins of life scenarios A key question concerned the fact that proteins are re quired for the synthesis of DNA yet the synthesis of these proteins is coded for by DNA Which came first DNA or proteins How could DNA store genetic infor mation if there were no enzymes to catalyze the polymerization of its nucleotide components How could there be proteins if there were no DNA to code for them ... [Pg.1177]

This level of simplicity is not the usual case in the systems that are of interest to chemical engineers. The complexity we will encounter will be much higher and will involve more detailed issues on the right-hand side of the equations we work with. Instead of a constant or some explicit function of time, the function will be an explicit function of one or more key characterizing variables of the system and implicit in time. The reason for this is that of cause. Time in and of itself is never a physical or chemical cause—it is simply the independent variable. When we need to deal with the analysis of more complex systems the mechanism that causes the change we are modeling becomes all important. Therefore we look for descriptions that will be dependent on the mechanism of change. In fact, we can learn about the mechanism of... [Pg.113]


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