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Kamlet-Taft solvent

Kamlet-Taft solvent parameters, 2, 123 Kanamycins episulfides... [Pg.693]

Equations containing a number of solvent parameters in linear or multiple linear regression and expressing the effect of the solvent on the rate of the reaction or the thermodynamic equilibrium constant. See Ej Values Kamlet-Taft Solvent Parameter Koppel-Palm Solvent Parameter Z Value... [Pg.426]

The averaged Kamlet-Taft solvent basicity scale / kt was established by averaging similar values of /J obtained within narrow limits for several homomorphic HBD and non-HBD... [Pg.375]

Kamlet-Taft solvent parameters Parameters of the Kamlet-Taft solvatochromic relationship that measure separately the hydrogen bond donor (a), hydrogen bond acceptor (P), and dipolarity/POLARiZABiLiTY (ji ) properties of solvents as contributing to overall solvent POLARITY. [Pg.153]

KAMLET-TaFT SOLVENT PARAMETER KOPPEL-PALM SOLVENT PARAMETER STABILITY CONSTANT Z-VALUE. [Pg.166]

GRUNWALD-WlNSTEIN EQUATION IONIZING POWER KAMLET-TAFT SOLVENT PARAMETERS Z-VALUE. [Pg.216]

GRUNWALD-WlNSTEIN EQUATION KAMLET-TAFT SOLVENT PARAMETERS KOPPEL-PALM SOLVENT PARAMETERS SOLVOPHOBICITY PARAMETER Z-VALUE. [Pg.252]

More recent solvatochromic studies [14-20] employ specialised dyes reflecting specific microscopic molecular interactions. For example, the Abboud-Kamlet-Taft solvent parameters [21-23] a, 3 and n give information on hydrogen bond donor and acceptor properties and the polarisability of a compound, respectively. For ionic liquids with [C4mim]-cations, the following order of [3- values was estab-... [Pg.47]

Crowhurst L, Falcone R, Lancaster NL et al. (2006) Using Kamlet-Taft solvent descriptors to explain the reactivity of anionic nucleophiles in ionic liquids. J Org Chem 71 8847-8853... [Pg.207]

FIGURE 9. Correlation of the fluorescence spectra of HPTA in pure solvents with the Kamlet-Taft solvent-polarity parameters ... [Pg.504]

FIGURE 20. The poor correlation found between the fluorescence maximum of IN and solvent polarity using Kamlet-Taft solvent-polarity parameters of 15 common solvents (from Reference 91)... [Pg.514]

Figure 9.16 LSER correlation of initial rate constant with Kamlet-Taft solvent parameters. ... Figure 9.16 LSER correlation of initial rate constant with Kamlet-Taft solvent parameters. ...
Lu, J., Brown, J.S., Liotta, C.L. and Eckert, C.A., Polarity and hydrogen-bonding of ambient to near-critical water Kamlet-Taft solvent parameters, Chem. Commun., 2001, (7), 665-666. [Pg.298]

Table 1. Absorption maxima of Neutral Red (NR) in various solvents and selective Kamlet-Taft solvent properties. Table 1. Absorption maxima of Neutral Red (NR) in various solvents and selective Kamlet-Taft solvent properties.
What seems to be happening is that, though the solvent does produce an effect on AG°, at the same time there is a change in the bond order of the transition state, rfi. According to Figure 9.2, this can be correlated with the Kamlet-Taft solvent parameter which is an empirical measure of the capacity of the solvent to coordinate via the donation of a pair of non-bonding electrons, i.e. the solvent acts as a Lewis base. [Pg.224]

See other pages where Kamlet-Taft solvent is mentioned: [Pg.395]    [Pg.754]    [Pg.123]    [Pg.123]    [Pg.250]    [Pg.463]    [Pg.281]    [Pg.263]    [Pg.40]    [Pg.14]    [Pg.800]   


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Kamlet-Taft

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