Inductively coupled plasma mass isotope dilution

In isotope dilution inductively coupled plasma-mass spectrometry (ID-ICP-MS) the spike, the unspiked and a spiked sample are measured by ICP-MS in order to determine the isotope ratio. Using this technique, more precise and accurate results can be obtained than by using a calibration graph or by standard addition. This is due to elimination of various systematic errors. Isotopes behave identically in most chemical and physical processes. Signal suppression and enhancement due to the matrix in ICP-MS affects both isotopes equally. The same holds for most long-term instrumental fluctuations and drift. Accuracy and precision obtained with ID-ICP-QMS are better than with other ICP-QMS calibration... [Pg.660]

B.7 Introduction to Isotope Dilution Inductively Coupled Plasma Mass Spectrometry... [Pg.176]

Klinkhammer, G.P., and L.H. Chan. 1990. Determination of barium in marine waters by isotope dilution inductively coupled plasma mass spectrometry. Anal. Chim. Acta 232 323-329. [Pg.95]

Ohtsuka, Y., Takaku, Y., Kimura, J., Hisamatsu, S., and Inaba, J., Development of rapid plutonium analysis for environmental samples by isotope dilution/inductively coupled plasma mass spectrometry with on-line column, Anal. Sci., 21, 205-208, 2005. [Pg.557]

Colodner, D.C., Boyle, E.A. and Edmond, J.M. (1993) Determination of rhenium and platinum in natural waters and sediments, and iridium in sediments by flow injection isotope dilution inductively coupled plasma mass spectrometry. Anal. Client., 65, 1419-1425. [Pg.354]

E. Vassileva, C. Quetel, CertiPcation of the cadmium, copper and lead amount content in IMEP-19 by Isotope Dilution Inductively Coupled Plasma Mass Spectrometry, Internal Reports GE/R/IM/04/2002/01/31, GE/R/IM/05/2002/01/31, GE/R/IM/ 06/2002/01/31. [Pg.219]

Briichert, W., Kruger, R., Tholey, A., Montes-Bayon, M., Bettmer, J. A novel approach for analysis of oligonucleotide-cisplatin interactions by continuous elution gel electrophoresis coupled to isotope dilution inductively coupled plasma mass spectrometry and matrix-assisted laser desorption/ionization mass spectrometry. Electrophoresis 29, 1451-1459 (2008)... [Pg.399]

Beals, D.M., Determination of Technetium-99 in aqueous samples by isotope dilution inductively coupled plasma-mass spectrometry. Proceedings of 3rd Annual Conference on Nuclear and Radiochemistry, Vienna, Sept. 1992. [Pg.248]

Pin, C., Lacombe, S., Telouk, P. and Imbert, J.-L., Isotope dilution inductively coupled plasma mass spectrometry a straightforward method for rapid and accurate determination of uranium and thorium... [Pg.255]

Beary ES, Paulsen PJ and Fassett JD (1994) Sample preparation approaches for isotope dilution inductively coupled plasma mass spectrometric certification of reference materials. J Anal Atom Spectrosc 9 1363-1369. [Pg.746]

Yi YV and Masuda A (1996) Simultaneous determination of Ru, Pd, Ir, and Pt at ultra trace levels by isotope dilution Inductively coupled plasma mass spectrometry in geological samples. Anal Chem 68 1444-1450. [Pg.1085]

ID-ICP-MS isotope dilution inductively coupled plasma mass spectrometry IDLH value Immediately Dangerous to Life and Health dose of a toxic substance (NIOSH)... [Pg.1686]

McKelvey BA and Orians KJ (1998) The determination of dissolved zirconium and hafnium from seawater using isotope dilution inductively coupled plasma mass spectrometry. Marine Chemistry 60 245-255. [Pg.63]

Catterick, T., Fairman, B. and Harrington C.F., Structured approach to achieving high accuracy measurements with isotope dilution inductively coupled plasma mass spectrometry, J. Anal. At. Spectrom., 13, 1009-1013 (1998). [Pg.46]

ICCIDD International Council for Control of Iodine Deficiency Disorders ICP-MS Isotope dilution inductively coupled plasma mass spectrometry IDD Iodine deficiency disorders... [Pg.1129]

UI was analyzed for NHANES III using the SandeU-Kolthoff colorimetric method (SandeU and Kolthoff, 1937), whereas isotope dilution inductively coupled plasma mass spectrometry (ICP-MS) was used for urine iodide analysis of the iodine measured in NHANES 2001— 2002 (Allain et al., 1990). Therefore, data from NHANES III should be compared cautiously with that obtained in NHANES 2001-2002 (Soldin, 2002 Caldwell et ai, 2003 Haldimann et ai, 1998). [Pg.1131]

Haldimann, M., Baduraux, M., Eastgate, A., Froidevaux, P., O Donovan, S., Von Gunten, D., and Zoller, O. 2001. Determining picogram quantities of uranium in urine by isotope dilution inductively coupled plasma mass spectrometry. Comparison with alpha-spectrometry. J Anal Atom Spectrom 16(12), 1364—1369. [Pg.447]

Beals, D.M. Determination of Technetium-99 in Aqueous Samples by Isotope Dilution Inductively Coupled Plasma-Mass Spectrometry, Westinhouse Savannah River Company, Aiken, SC. [Pg.94]

H.-W. Liu, S.-J. Jiang, and S.-H. Liu. Determination of cadmium, mercury and lead in seawater by electrothermal vaporization isotope dilution inductively coupled plasma mass spectrometry. Spectrochimica Acta Part B 54 1367-1375,1999. [Pg.302]

Brown A, Ebdon L, Hill S (1994) Development of a coupled liquid chromatography isotope dilution inductively coupled plasma mass spectrometry method for lead speciation. Anal Chim Acta 286 391-399. [Pg.34]

Baker, S. A., Smith, B.W., and Winefordner, J. D. (1997). Determination of trace amount of lead in natural waterby isotope dilution -inductively coupled plasma mass spectrometry. Investigation of light scattering for normalization of signals in laser ablation inductively coupled plasma mass spectrometry. Ami. Sci. Int.J.Jpn. Soc.Anal. Chein. 52(1), 7. [Pg.192]

Beary, E. S., Paulsen, P. J.,Jassie, L. B., and Fassett,J. D. (1997). Determination of environmental lead using continuous-flow microwave digestion isotope dilution inductively coupled plasma mass spectrometry. Anal. Chem. 69(4), 758. [Pg.194]

Bowins, R. J., and McNutt, R. H. (1994). Electrothermal isotope dilution inductively coupled plasma mass spectrometry method for the determination of sub-ng levels of lead in human phsms.J. Anal. At. Spectrom. 9(11), 1233. [Pg.198]

Chang, C. C., and Jiang, S.J. (1997). Determination of copper, cadmium and lead in biological samples by electrothermal vaporization isotope dilution inductively coupled plasma mass spectrometry.J. Anal. At. Spectrom. 12(1), 75. [Pg.201]

Chartier, E, Aubert, M., and Pilier, M. (1999). Determination of Am and Cm in spent nuclear fuels by isotope dilution inductively coupled plasma mass spectrometry and isotope dilution thermal ionization mass spectrometry after separation by high-performance liquid chromatography. Fresenius J.Anal. Chem. 364(4), 320. [Pg.201]

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