Isopropyl peroxydicarbonate

ISOPROPYL PEROXYDICARBONATE see DI-ISOPROPYL PEROXY-ISOPROPYL PROPIONATE 2409 637-78-5... 

Chemical Designations - Synonyms Diisopropyl percarbonate Diisopropyl peroxydicarbonate Isopropyl peroxydicarbonate Peroxydicarbonic acid, bis (1-methylethyl) ester Peroxydicarbonic acid, diisopropyl ester Chemical Formula C3H7OOCOOCOOC3H7. 

Imidoyl radicals are often prepared by the addition of carbon- or heteroatom-centred radicals to isocyanides, but can also be prepared by hydrogen atom abstraction from imines. This latter method has been adopted in a new annulation approach to quinoline synthesis. Thus, reaction of the imine 1 with phenylacetylene and di-isopropyl peroxydicarbonate in benzene at 60°C gave a mixture of the quinolines 2 and 3 in 65% yield (2 3 = 4.4). 

SYNS DIISOPROPYL PEROXYDICARBONATE ISOPROPYL PERCARBONATE ISOPROPYL PEROXYDICARBONATE PEROXYDICARBONATE d ISOPROPYLE PEROXYDICARBONIC ACID, BIS(1-METHYLETHYL) ESTER... 

ISOPROPYLOXYPROPYLENE OXIDE see IPDOOO ISOPROPYL PERCARBONATE see DNR400 ISOPROPYL PEROXYDICARBONATE see DNR400 ISOPROPYLPHENAZONE see INYOOO... 

Arylideneanilines are converted into fused pyridines by heating with an alkyne and an oxidizing agent such as di-isopropyl peroxydicarbonate (DP) when the aniline is unsymmetrically substituted, a mixture of isomers may be formed [3173]. a-Halo ketones (and, less efficiently, simple aliphatic ketones [2639]) react with imines to give fused pyridines in variable yields [2715]. An imine formed by reaction of a 6-aminopyrimidinedione with DMFDMA undergoes cycloaddition with an electron-deficient alkene the first product is dehydrogenated in hot nitrobenzene [3620]. 

Beilstein Handbook Reference) Bisisopropyl peroxydicarbonate BRN 1786996 Diisopropyl perdicarbonate Diisopropyl peroxy-dicarbonate Diisopropyl peroxydiformale EINECS 203-317-4 HSDB 349 Isopropyl percarbonate Isopropyl peroxydicarbonate Luperox IPP Peroxydicarbonate d isopropyle Petoxydicarbonic acid, bis(l-methylethyl) ester Peroxydicarbonic acid, diisopropyl ester. 

Synonyms isopropyl peroxydicarbonate per-oxydicarbonic acid diisopropyl ester diisopropyl perdicarbonate isopropyl percar-bonate... 

Benzoyl peroxide (over 98%), t-Butyl hydroperoxide (over 90%), di-isopropyl peroxydicarbonate (100%)... 

Isopropyl pentanoate. See Isopropyl valerate Isopropyl percarbonate Isopropyl peroxydicarbonate. See Diisopropyl perdicarbonate... 

Further monomer-soluble initiators mentioned in patents are di(2-ethylhexanoyl) peroxide [345], 3,5,5-trimethylhexanoyl peroxide [346], di(f-butyl) peroxyoxalate [347], di(carballyloxy isopropyl peroxydicarbonate) [348], di-2-butoxyethyl peroxydicarbonate [349], and di-4-chlorobutyl peroxydicarbonate [350]. An elegant initiation technique for polymerization of VC is described by Ravey and Waterman [351]. They investigated the in situ formation of the initiator during reaction from stable precursors. This method avoids the problem of handling unstable initiators. Furthermore, the in situ mode proved to be more efficient at lower temperatures than the conventional systems [352]. 

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