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Iron Azide

Iron Azide or Ferric Triazide was prepd in soln by T. Curtius J. Rissom, but it was not until 1917 when L. Wohler F. Martin prepd it again and isolated it (Vol 1 of Encycl, pp A543-L to A544-L)... [Pg.148]

Iron Azide. See List of Inorganic Azides in Vol 1, p A543... [Pg.398]

Iron Azide or Ferric Triazide, Fe(N3)j or [Fe(Nj)] (N,)2, mw 181.92, N 69.30% dk brn hygro lfts easily hydrolyzed and very wr stable, mp-expl 200c(Ref 10). It was first prepd and isolated, in 1917 by Wohler Martin (Ref 5), by treating dry ferric sulfate with sodium... [Pg.543]

XIII) Killing Tank at KOW contained, according to Ref 9, p 59, various waste liquids and slurries in which azides are likely to be present. When a sufficient quantity of such material was accumulated (not less than 1000 liters), the operator stirred the contents of the tank and took a 6 02 sample. If a small portion of the sample gave a positive test for azides (a red ppt of iron azide obtained on adding few drops of 1% feCl3 soln), a quantitative test was conducted as follows ... [Pg.573]

Ferric Azide A543-L Ferric Azide, Basic A543-R Ferric Triazide. See Iron Azide A543-L Ferrous Acetylide. See Iron Acetylide A76-R... [Pg.682]

The iron from the capsule experiments was brittle and fell apart when rubbed. In this investigation iron azide (ferric or ferrous azide) and hydrazine could not be detected, contrary to the work of Franklin [51] and Curtius and Risson [52]. Polyethylene becomes brittle, opaque, and porous when exposed to hydrazoic acid, and hydrazoic acid diffused through 0.008 in polyethylene bags within 90 days. Blay and Dunstan [53] reported little azide interaction with polyethylene, but noted a marked drop in azide value when Service lead azide was in contact with various rubbers, plastics, and other synthetic packaging materials. A reduction in azide content as high as 70% was shown (Figure 4). This was attributed to the slow release of carbon dioxide from the test material, followed by further hydrolysis of the lead azide. [Pg.95]


See other pages where Iron Azide is mentioned: [Pg.476]    [Pg.684]    [Pg.543]    [Pg.684]    [Pg.684]    [Pg.684]   
See also in sourсe #XX -- [ Pg.543 ]

See also in sourсe #XX -- [ Pg.543 , Pg.544 ]

See also in sourсe #XX -- [ Pg.543 ]

See also in sourсe #XX -- [ Pg.543 ]

See also in sourсe #XX -- [ Pg.543 ]

See also in sourсe #XX -- [ Pg.543 ]




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