Interfacial stresses difference method model

Sigillo et al. (1997) used several experimental methods for the measurement of interfacial tension of a model polymer blend. Common to all methods presented here are two main points. The first is that a is obtained from experiments where the shape of the interface between the liquids is directly observed by means of optical microscopy techniques. The second point is that the interface geometry is controlled by a balance between the interfacial force and the viscous stresses generated by some flow applied to the system. Measurements have been carried out on a model polymer blend, whose constituents are a polyisobutylene and a polydimethylsiloxane, both transparent and liquid at room temperature. When compared with each other, the values of interfacial tension obtained from the different methods show a good quantitative agreement. Excellent agreement is also found with results for the same system previously published in the literature. 

The remaining part of this chapter will review the three most common direct methods for measuring fiber-matrix adhesion, focusing on the sample preparation and fabrication, the experimental protocols and the underlying theoretical analyses upon which evaluation of these methods are based. In addition, finite-element nonlinear analyses and photoelastic analyses will be used to identify differences in the state of stress that is induced in each specimen model of the three different techniques. In order to provide an objective comparison between the three different techniques to measure the interfacial shear strength for the prospective user, data and a carbon fiber-epoxy resin system will be used as a baseline system throughout this chapter, However, these methods and procedures can be applied for adhesion measurements to any fiber-matrix combination. 

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