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Interconnection problem

The variational theorem which has been initially proved in 1907 (24), before the birthday of the Quantum Mechanics, has given rise to a method widely employed in Qnantnm calculations. The finite-field method, developed by Cohen andRoothan (25), is coimected to this method. The Stark Hamiltonian —fi.S explicitly appears in the Fock monoelectronic operator. The polarizability is derived from the second derivative of the energy with respect to the electric field. The finite-field method has been developed at the SCF and Cl levels but the difficulty of such a method is the well known loss in the numerical precision in the limit of small or strong fields. The latter case poses several interconnected problems in the calculation of polarizability at a given order, n ... [Pg.271]

There are two interconnected problems which could prevent Nuclear Energy from expanding to meet coming world needs. [Pg.103]

We are faced with two interconnected problems related to the intelligibility of the presentation. The first one concerns the nomenclature of the centres other than isolated atoms and the second the labelling of the optical transitions. These problems are not trivial, [5], but not as severe for H-like centres as for deep centres. The different notations for the shallow thermal donor complexes in silicon, discussed in Sect. 6.4.2, are however, a counter-example of this statement. In this book, on the basis of the present knowledge, names of centres, in direct relation with their atomic structure, have been privileged, but the usual label has however been indicated. When the exact structure is not simple and when there exist an acronym, like TDD for thermal double donor , it has been used. The labelling by their excited states of the transitions of the shallow donor centres and of similar species, whose spectra... [Pg.17]

Applications for measurements of rapidly moving, vibrating, or rotating parts, because interconnecting problems would arise for matter-based principles. [Pg.32]

Inadequate stoichiometry and poor calibration of the analytical device are interconnected problems. The kinetic model itself follows the stoichiometric rules, but an inadequate calibration of the analytical instrument causes systematic deviations. This can be illustrated with a simple example. Assume diat a bimolecular reaction, A + B P, is carried out in a liquid-phase batch reactor. The density of the reaction mixture is assumed to be constant. The reaction is started with A and B, and no P is present in the initial mixture. The concentrations are related by cp=CoA-Cj=Cob -Cb, i e. produced product, P, equals with consumed reactant. If the concentration of the component B has a calibration error, we get instead of the correct concentration cb an erroneous one, c n ncs, which does not fulfil the stoichiometric relation. If the error is large for a single component, it is easy to recognize, but the situation can be much worse calibration errors are present in several components and all of their effects are spread during nonlinear regression, in the estimation of the model parameters. This is reflected by the fact that the total mass balance is not fulfilled by the experimental data. A way to check the analytical data is to use some fonns of total balances, e.g. atom balances or total molar amounts or concentrations. For example, for the model reaction, A + B P, we have the relation ca+cb+cp -c()a+c0 -constant (again c0p=0). [Pg.447]

Let us first examine some aspects of the interconnected problem of atomic weights, formulas, and molecular magnitudes. In chapter 1 we noted much disunity and confusion in the chemical community on these questions, such as the crucial issue of the formula for water. What Williamson had done in 1850-51 was to present the first direct experimentally based argument that in the water molecule there really is one indivisible oxygen atom weighing 16. That water really is H2O... [Pg.79]

It is theoretically possible, that the problem of the radioactive wastes of the primary circuit, except for the spent fuel and fission products (S/A), can be solved without their disposal, if the wastes are stored in the intermediate storage during 50 or 100 years. In order to do this, several interconnected problems should be solved. [Pg.168]

Below we investigate all fluxes in the course of evaporation process in a self consistent way we study the interconnected problem of vapour transfer, heat transfer in the vapour, the liquid and the solid substrate, and Marangoni convection inside the liquid droplet... [Pg.116]

Under a number of reasonable approximations the evaporation of small enough sessile droplets has been investigated in a self cOTisistent way by considering the interconnected problem of vapour transfer heat transfer in vapour, liquid and solid support and the Marangoni convection inside the liquid droplet The influence of the thermal conductivity of the solid support on the evaporation process has been analyzed. The calculated total evaporation flux has been compared with the result in the case of isothermal evaporation. It has been shown that the lower the thermal conductivity of the solid support the higher the deviations appear from the isothermal case. However, if the mean temperature of the droplet surface is used instead of the temperature of the surrounding air for the vapour concentration on the droplet surface flien the results found coincide with those known for the isothermal case. [Pg.119]

In addition to this, the overall system reliability can be decreased due to electrical failures caused by an increasing number of connectors and wires. For example, in the automotive domain field data has shown that between 30 — 60% of electrical failures are attributed to connector problems [38]. In the aerospace domain interconnection problems are also a major cause of aircraft electrical equipment failures with a percentage of 36% [16] / 43% [35]. [Pg.5]

The jS-lactam-thiazohdine ring system in the penicillins is replaced in cephalosporin C by a j8-lactam-dihydrothiazine ring system. The structural relationship of these two ring systems, coupled with the fact that penicillin N and cephalosporin C have the same (3-(D-a-aminoadipoyl) side chain, indicated that the penicillin and cephalosporin series were biogenetically related and that interconnected problems would arise in studies of their biosynthesis. [Pg.2]


See other pages where Interconnection problem is mentioned: [Pg.220]    [Pg.225]    [Pg.449]    [Pg.117]    [Pg.311]    [Pg.111]    [Pg.133]    [Pg.8]    [Pg.27]    [Pg.354]    [Pg.189]    [Pg.314]    [Pg.278]    [Pg.408]   
See also in sourсe #XX -- [ Pg.441 ]




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