Infra-red spectroscopic studies

Crisp, S., Prosser, H. J. Wilson, A. D. (1976). An infra-red spectroscopic study of cement formation between metal oxides and aqueous solutions of poly(acrylic acid). Journal of Materials Science, 11, 36-48. 

Wilson, A. D. Mesley, R. J. (1972). Zinc oxide eugenol cements. III. Infra-red spectroscopic studies. Journal of Dental Research, 51, I58I-8. 

Stereochemistry. - There has been a far infra-red spectroscopic study of ethyl phosphine,130 and in combination with X-ray fluorescence, further work completed on the conformational analysis of dialkylphenyl phosphines.131 The influence of water on the conformational equilibria of trimethyl phosphate has received attention.132 There has been a low temperature solid state and matrix isolation study of methyl phosphorodichi oridate,133 and a conformational study of polymorphic modifications of diphenyl-phosphinyl acetic acid hydrazide. 34... 

The physical and chemical properties of MgO films prepared by the sol-gel technique were the area interest of the examinations presented by Shukla75. The aim of mentioned work was to produce films with nano size particles so as to employ them for the sensor applications, as adsorption in such films increases many folds due to the increase of surface area. Infra-red spectroscopic studies indicated the presence of solvent in the precursor, which helped in decomposition to nano-particles during nucleation of the film. The MgO sol-gel films were deposited on the glass rod bend in U-shape for humidity sensor. 

Figure 4.10 Reprinted from Tribol. Int., Vol. 25, P.A. Willermet, R.O. Carter, III and N.E. Boulos, Lubricant-derived tribochemical films-An infra-red spectroscopic study, pp. 371-380. Copyright 1992, with permission from Elsevier.

The proposed metalation process involving the formation of a putative zinc acetylide was substantiated by a series of infra-red spectroscopic studies (Fig. 2) [12]. The synergistic effect in the deprotonation event of the zinc salt... 

Liddel U, Becker ED. Infra-red spectroscopic studies of hydrogen bonding in methanol, ethanol, and f-butanol. Spectrochem Acta 1957 10 70-84. 

On, S. F. D., Infra-red spectroscopic studies of some polysaccharides. Bio-chim. Biophys. Acta 14, 173-181 (1954). 

On the other hand, infra red spectroscopic studies indicate that this resonance stabilization does not occur with thioesters. 

The doubly-bonded (bridged) OH groups, formed according to Eq. (2), become thus Bronsted acid centers, while the singly-bonded (terminal) hydroxyls are expected to exhibit a predominantly basic character A large amount of reliable data regarding the interaction of water with titanium dioxide, are provided by infra-red spectroscopic studies associated with temperature-programmed desorption measurements. 

Kusanagi, H. and Yukawa, S. Fourier transform infra-red spectroscopic studies of water molecules sorbed in solid polymers. Polymer, 35, 5637,1994. 

Matveevicheva, V., 1969, X-ray diffraction and infra red spectroscopic study of the phase composition of the oxide system Vp - MgO. Rus. J. Phys. Chem. 43, 143. 

Reprinted with permission of Elsevier Science from Cunningham, A., Ward, I. M., Willis, H. A. and Zichy, V., An infra-red spectroscopic study of molecular orientation and conformational changes in poly(ethylene terephthalate) . Polymer 15, 749-756. Copyright 1974. 

H.J. Prosser, B. Stuart, A.D. Wilson, An infra-red spectroscopic study of the setting reaction of a calcium hydroxide dental cement, J. Mater. Sci. 14 (1979) 2894-2900. 

Kusanagi H, Yukawa S (1994) Fourier transform infra-red spectroscopic studies of water molecules sorbed in solid polymers. Polymer 35(26) 5637-5640 Li L, Zhang S, Chen Y, Liu M, Ding Y, Luo X, Pu Z, Zhou W, Li S (2005) Water transportation in epoxy resin. Chem Mater 17(4) 839-845 Luikov AV (1968) Analytical heat diffusion theory. Academic, New York Marechal Y, Charnel A (1996) Water in a biomembrane by infrared spectrometry. J Phys Chem 100(20) 8551-8555... 

It is understandable that pyrrole should possess a finite dipole moment (p. 51). Further, the resonance description requires the molecule to be planar. The classical structure (15) could accommodate a pyramidal nitrogen atom, but although dipole-moment studies allow the extra-annular nitrogen valency an out-of-plane latitude of 7°, and Raman and infra-red spectroscopic studies favour the planar form but do not rigorously exclude a non-planar formas, the microwave rotational spectrum confirms the truly planar structure (18). 

T. Yokono, S. Shimokawa, M. Yokono, H. Hattori, Infra-red spectroscopic study of structural change of liquid water induced by sunlight irradiation. Water 1, 29-34 (2009)... 

An important mechanistic aspect of the Cu-bisphosphine-catalyzed addition reactions of dienolates to aldehydes is worth highlighting. Infra-red spectroscopic studies have collectively provided insight into the details of this process. In this respect, these processes have been suggested to proceed through metaloenolate intermediates [146]. As such, the process complements the traditional Mukaiyama aldol addition reaction, which typically proceeds through Lewis activation of the electrophilic aldehyde partner. 

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