Inductively coupled plasma mass spectrometric

A novel interface to connect a ce system with an inductively coupled plasma mass spectrometric (icpms) detector has been developed (88). The interface was built using a direct injection nebulizer (din) system. The ce/din/icpms system was evaluated using samples containing selected alkah, alkaline earths, and heavy-metal ions, as well as selenium (Se(IV) and Se(VI)), and various inorganic and organic arsenic species. The preliminary results show that the system can be used to determine metal species at ppt to ppb level. 

Creed JT, and Brockhoff CA (1999) Isotope dilution analysis of bromate in drinking water matrixes by ion chromatography with inductively coupled plasma mass spectrometric detection. Anal Chem 71 722-726. 

Zheng, J., Kosmus, W., Pichler-Semmelrock, F., and Kock, M., Arsenic speci-ation in human urine reference materials using high-performance liquid chromatography with inductively coupled plasma mass spectrometric detection, /. Trace Elements Med. Biol., 13, 150, 1999. 

Creed et al. [68] described a hydride generation inductively coupled plasma mass spectrometric method featuring a tubular membrane gas-liquid separator for the determination of down to 100 pg of arsenic in seawater. 

Bloxam et al. [482] used liquid chromatography with an inductively coupled plasma mass spectrometric detector in speciation studies on ppt levels of mercury in seawater. 

Goossens J, Moens L, Dams R. Inductively coupled plasma mass spectrometric determination of heavy metals in soil and sludge candidate reference materials. Anal. Chim. Acta 1995 304 307-315. 

A hyphenated technique, the coupling of ion chromatographic separation (DX-100, DIONEX) and inductively coupled plasma mass spectrometric detection (ELAN-5000, PERKIN-ELMER) was used for the speciation... 

Yang et al. [83] accomplished speciation of organotin compounds using reverse-phase liquid chromatography with inductively coupled plasma mass spectrometric detection. The separation was complete in 6min and detection limits were in the range 2.8-16pg of tin for various species. 

Sutton, K., Sutton, R. M. C., and Caruso, J. A. (1997). Inductively coupled plasma mass spectrometric detection for chromatography and capillary electrophoresis.. Chromatogr. A 789, 85-126. 

Thompson, J. J. and Houk, R. S., Inductively coupled plasma mass spectrometric detection for multielement flow injection analysis and elemental speciation by reversed phase liquid chromatography, Anal. Chem., 58, 2541-2548, 1986. 

Boulyga et al. [51,52] characterised different inductively coupled plasma mass spectrometric configurations for the determination of the 236u/238U ratio and 240Pu/239Pu ratio in soil. 

Carey, J.M., Vela, N.P. and Caruso, J.A. (1994) Chromium determination by supercritical fluid chromatography with inductively coupled plasma mass spectrometric detection. J. Chromatogr., 642, 329-340. 

Magnuson, M.L., Creed, J.T. and Brocklioff C.A. (1997) Speciation of selenium and arsenic compounds by capillary electrophoresis with hydrodynamically modified electroosmatic flow and on-line reduction of selenium (VI) to selenium (IV) with hydride generation inductively coupled plasma mass spectrometric detection. Analyst, 122, 1057-1061. 

Grant, T.D., R.G. Wuilloud, J.C. WuiUoud, et al. 2004. Investigation of the elemental composition and chemical association of several elements in fulvic acids dietary supplements by size-exclusion chromatography UV inductively coupled plasma mass spectrometric. J. Chmmatogr. A 1054 313-319. 

Henshaw JM, Heithmar EM, Hinners TA. 1989. Inductively coupled plasma mass spectrometric determination of trace elements in surface waters subject to acidic deposition. Anal Chem 61 335-342. 

Longerich, H.P. (1989) The effect of nitric acid, acetic acid and ethanol on inductively coupled plasma-mass spectrometric ion signals as a function of nebulizer gas flow, with implications on matrix suppression and enhancements. J. Anal. Atomic Spectroscopy 4, 665-677. 

Inductively Coupled Plasma Mass Spectrometric Detection... 

Montes-Bayon, M., B Hymer, C., Ponce de Leon, C., and Caruso, J.A. 2001. Resolution of seleno-amino acid optical isomers using chiral derivatization and inductively coupled plasma mass spectrometric (ICP-MS) detection. J. Anal. At. Spectrom. 16(9), 945-950. 

A. Krushevska, A. Lasztity, M. Kotrebai, R. M. Barnes, Addition of tertiary amines in the semiquantitative, multi-element inductively coupled plasma mass spectrometric analysis of biological materials, J. Anal. Atom. Spectrom., 11 (1996), 343D352. 

B. Bouyssiere, J. Szpunar, R. Lobinski, Gas chromatography with inductively coupled plasma mass spectrometric detection in speciation analysis, Spectrochim. Acta, 57B (2002), 805 D 828. 

L. Fernandez Sanchez, J. Szpunar, Speciation analysis for iodine in milk by size-exclusion chromatography with inductively coupled plasma mass spectrometric detection (SEC-ICP MS), J. Anal. Atom. Spectrom., 14 (1999), 1697D1703. 

Segovia Garcia, E., Garcia Alonso, J.I., Sanz Medel, A. Determination of butyltin compounds in sediments by means of hydride generation/cold trapping gas chromatography coupled to inductively coupled plasma mass spectrometric detection. J. Mass Spectrom. 32, 542-549 (1997)... 

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