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Individuals, xvii

Tables IV-XVI show that the tetraalkylammonium salts have a large effect on both solvents in the binary solvent mixture, especially the larger tetraalkylammonium bromides, i.e., (n-C3H7)4NBr and (n-C4Hg)4NBr. This can be seen from consideration of the boiling temperature alone. This observation is also borne out by the surface tensions and solubilities at 25°C of the individual salts studied, the results of which are tabulated in Table XVII in water, in ethanol, and in an ethanol-water mixture at x = 0.206. For the higher homologs of the R4NBr series, these salts exert a large effect on the surface tensions of the solvent systems studied and show a marked increase in their solubility in ethanol. Tables IV-XVI show that the tetraalkylammonium salts have a large effect on both solvents in the binary solvent mixture, especially the larger tetraalkylammonium bromides, i.e., (n-C3H7)4NBr and (n-C4Hg)4NBr. This can be seen from consideration of the boiling temperature alone. This observation is also borne out by the surface tensions and solubilities at 25°C of the individual salts studied, the results of which are tabulated in Table XVII in water, in ethanol, and in an ethanol-water mixture at x = 0.206. For the higher homologs of the R4NBr series, these salts exert a large effect on the surface tensions of the solvent systems studied and show a marked increase in their solubility in ethanol.
If only a few experimental data or calculated results are involved, they can be displayed in the body of the text as an unnumbered tabulation centered horizontally with wider margins than the text (see Sec. Ill of the Sample Report). In many cases, extensive data sets or multiple calculated results are obtained. These are best presented in formal tables with a number, a self-explanatory caption, and clearly labeled column heads with units given in parentheses. Footnotes may also be used at the bottom of the table to include references or comments on individual entries. See Tables 47-2 and XVII-1 as examples. [Pg.12]

An example of a tt-bonded complex is the remarkable cyanine oxonol system, 3-XVI 3-XVII, for which at least fourteen different polymorphs or solvates have been identified (Etter et al. 1984). Two of these, a gold and a red form (each containing a molecule of CHCI3 solvent per 1 1 complex, and hence true polymorphs) crystallize concomitantly and have been structurally characterized (Etter et al. 1984). Three of these polymorphs are shown in Fig. 3.2. Despite the fact that both of these dye molecules are known to be individually self aggregating (Cash 1981) the two... [Pg.81]

Table XVII shows similar comparisons of the deviations from the first rule of the mean for an 0-disproportionation between carbon dioxide species. Here, the normal modes have been divided into 2 linear modes and 2 non-linear modes. The approximations for the non-linear modes are much better than those for the linear modes, simply because v max for the former is only a quarter of v max for the latter. Calculations (not shown in the Table) made with the Chebyshev (L = 5) yielded In K s of 2.550 X 10 and 2.086 X 10 for n = 2 and 3, respectively, compared with the exact value of 3.546 X 10 at 300°K. Rule of the Mean tests are especially useful for examining the suitability of a polynomial to a particular molecule, because they permit an examination of the correspondence between individual terms of the expansion and motions of groups of atoms in the molecule. Table XVII shows similar comparisons of the deviations from the first rule of the mean for an 0-disproportionation between carbon dioxide species. Here, the normal modes have been divided into 2 linear modes and 2 non-linear modes. The approximations for the non-linear modes are much better than those for the linear modes, simply because v max for the former is only a quarter of v max for the latter. Calculations (not shown in the Table) made with the Chebyshev (L = 5) yielded In K s of 2.550 X 10 and 2.086 X 10 for n = 2 and 3, respectively, compared with the exact value of 3.546 X 10 at 300°K. Rule of the Mean tests are especially useful for examining the suitability of a polynomial to a particular molecule, because they permit an examination of the correspondence between individual terms of the expansion and motions of groups of atoms in the molecule.
For example, the conversion of triene XVII into the vinyl acetate derivative XVIII requires some bond reorganizations that may be difficult to visualize (see Scheme 2). Individual steps will be easier to contrive and understand by keeping those atoms and bonds not involved in the particular single operation in place. The combination of fixing atoms and bonds and later changes to realistic pictures gives a maximum of transparency and elegance to the sequence. Compare, for instance, routes A and B of Scheme 2. Atoms remain fixed in pathway A while B is a more realistic representation of the intermediates involved. [Pg.11]

NLD 1992 The chemical is severely restricted, in 1981, the use of methyl bromide as a soil disinfectant was prohibited. Based on Article 16a ofthe Dutch Pesticide Law of 1962, an exemption could, however, be granted based on individual requests. In the following period of time, the policies of the Government aimed at a further decrease in the use of methyl bromide. In 1992 methyl bromide was completely banned for use as a soil disinfectant. In 1996, two space fumigation products on the basis of methyl bromide were extended until 1 December 2001. (Reference (EP3) UNEP/FAO - PIC Circulars XIV, XV, XVI, XVII - 12/2001,6/2002, 12/2002,6/2003, )... [Pg.5]

Table 4.66 lists the standards in Sec. 1910.1001 through 1910.1052 of Title 29, Chap. XVII, Sec. 1910.1000. These standards are detailed sets of regulations for individual substances. In addition to setting exposure limits, they require exposure monitoring and medical surveillance of exposed employees. [Pg.383]

Volume XVII, Intersdence Publishing, Division of John Wiley Sons, New York. Comment These 15 chapters by individual authors deal with low-pressure ethylene copolymers over a broad range of compositions from elastic materials, block copolymers, and ethylene copolymers with styrene, and copolymers prepared with cationic and anionic methods. Each chapter includes references. [Pg.226]


See other pages where Individuals, xvii is mentioned: [Pg.632]    [Pg.2113]    [Pg.537]    [Pg.117]    [Pg.2113]    [Pg.439]    [Pg.236]    [Pg.72]    [Pg.11]    [Pg.182]    [Pg.88]    [Pg.290]    [Pg.419]    [Pg.421]    [Pg.191]    [Pg.3227]   
See also in sourсe #XX -- [ Pg.4 ]




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