I- Hexadecene

Chlorinization of hen7ene with stannic chloride catalyst Ferric-chloride-catalyzed hydrochlorination of I-hexadecene Hydrochlorination of octyl and dodecyl alcohols NH, in H2S04... 

Poly(A/-vinylpyrrolidone-co-I -hexadecene) (1 2) fonnamide, W Saturated hydrocarbons n-Propanol, w 186... 

Polywax 500 and 655 (polyethylene fraction with average molecular weights of 500 and 655, respectively), purchased from Baker Petrolite, Inc., was used to prepare simulated FT wax (i.e., solvent) for the evaluation of flltration performance with and without the presence of aliphatic alcohol and mono-olefin in the FT wax. 1-dodecanol (ACS reagent, > 98%, Sigma-Aldrich, Inc.) and 1-hexadecene (GC standard grade reagent, > 99.8%, Sigma-Aldrich, Inc.) were used as model... 

Camin, D.L., Forziati, A.F., Rossini, F. (1954) Physical properties of n-hexadecane, n-decylcyclopentane, n-decylcyclohexane, 1-hexadecene and n-decy I benzene. J. Phys. Chem. 58, 440-442. 

I 7 Well-Defined Surface Rhodium Siloxide Complexes and Their Application to Catalysis Table 7.5 Hydrosilylation of 1-hexadecene and allyl ethers by polyhydrosiloxane (7.1) . 

To obtain the first clue to the reaction mechanism, two hydrocarbons may be considered (1) 1-hexadecene (cetene), representing group I, and (2) isopropylbenzene (cumene), representing group II. What common property of the catalyst will explain the cracking patterns of both, in conformity with what is known of the chemical reactions of carbon compounds ... 

E/O co-polymerization reports with bis(cyclopentadienyl) complexes include ethylene/1-butene, ethylene/l-pentene,254 ethylene/4-methyl-l-pentene,516,522,523 ethylene/1-hexene,229,230,254,446,447,478,481,484,509,512-515, 517-519,522,524-530 ethyiene/1.octene(254,504,505,515,522,531-535 ethyiene/i decene,254,520 ethylene/1-dodecene,254,536 ethylene/1-tetradecene,254,532 ethylene/1-hexadecene,511,512,518,525 ethylene/1-octadecene.532,536... 

The incorporation of C in products with longer chains is not complete. One molecule per 18 C atoms was found to be radioactive in the C6-C29 fraction, formed in the presence of [ C]-ethanol tracer on a Co catalyst, as opposed to one in 60 on Fe.I With l-[ C]-hexadecene added to a 3301-thesis gas on Co/thoria catalyst, at 70% conversion, the relative molar activity of the Cie alkane (normalised to Cs = 100) was 291000, that of the C17-C20 fraction 6000 (constant), but the analogous values for C2-C14 were as small as 50 to 500, increasing linearly with larger alkanes. 

Table indicates that only a fraction of the C label from ethene was incorporated into chain growth products on Co and Fe catalysts. About the same amount of C (31%) was found in FT products formed with 1[ C]-1-propene, but only 18% when l-[ C]-l-hexadecene was applied.I About 50% of radioactive ethene gave methane, and 50% chain growth products on a Co catalyst, I the specific activity of higher products being practically constant between C4 and C32. Less than 10% of C from labelled ethene was incorporated into C10-C17 products, but the incorporation from C-ethanol was 60-80 times higher on a fused iron catalyst.The difference... 

HEPTYL-2-CYCL0HEXEN0NE, 61, 59 1-Hexadecene, 60, 13 HEXAFLUOROACETONE, 63, 154 Hexafluoropropene, 63, 154 HEXAHYDR0-2-(lH)-AZ0ClN0NE, 63, 188 2,3,3a,4,7,7a-Hexahydro-3a-hydroxy-7a-methyl-IH-i ndene-... 

Heath et al. (10) suggested that some crystalline compounds may give ano molous release rates. Subsequently, my coworkers and I found that 16 OH crystallizes from septa leaving a visible surface deposit and the release rate was faster than would be expected from the regression line of Equation 4 based on the lower members of this series (18). Tetradecanol did not show this effect. Since many E isomers of hexadecen-l-ol are crystalline, these compounds may also show this effect. Fortunately most Lepidopteran sex pheromones of 16 carbon alcohols have the Z configuration and do not crystallize from septa. 

Fig. 14.4.1.1. Schematic diagram of a two-phase bioreactor system for continuous 1-octanol production. [After reference 7]. 1 -Octanol i s produced from n-octane in hexadecene by Pseudomonas oleovorans or recombinant strains containing the alkane oxidation genes.

I-Aldehyde [13754-69-3]. 3JJlyl5-Tetramethyl-2-hexadecenaL Phytal. Constit. of Tetragonia tetragonoides. Oil. 

---