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Hypsicity

As an example, Scheme 4.10 and Table 4.8 summarize the hypsicity analysis for the Craig plan. Hypsicity indices for all plans are given in column 8 of Table 4.7. Figure 4.34 illustrates the change in oxidation level profiles as a function of reaction stage. It turns out that the Campos plan with the highest RME is also the one with an HI closest to the isohypsic condition of HI = 0. In Table 4.8 a check on the computation of 2 made by taking... [Pg.125]

Scheme 4.10 Craig synthesis of nicotine showing key atoms for hypsicity (oxidation level) analysis. Scheme 4.10 Craig synthesis of nicotine showing key atoms for hypsicity (oxidation level) analysis.
Figure 4.68 Hypsicity profiles for the Baran (a) and Wood (b) synthesis plans for welwitindolinone A. Figure 4.68 Hypsicity profiles for the Baran (a) and Wood (b) synthesis plans for welwitindolinone A.
MW fraction of reagents that absolutely do not end up in the final target molecule structure. Hypsicity index, HI... [Pg.87]

A parameter that tracks the oxidation length traversed over the course of a synthesis plan equal to the absolute value of the sum of all the ups and downs in a hypsicity profile or bar graph beginning with the zeroth reaction stage. [Pg.87]

Oxidation length, UD (counts the ups and downs in hypsicity profile)... [Pg.105]

For monotonic increases (hypohypsic profile) or monotonic decreases (hyperhypsic profile). lUDI is twice the height of the first bar in the hypsicity profile (see Figure 5.5 for verification). [Pg.105]

Hypsicity profile (Salsolene oxide-Wender plan)... [Pg.105]

FIGURE 5.4 Isohypsic hypsicity profiles (a) truly isohypsic and (b) by fortuitous algebraic cancellations of ups and downs. [Pg.105]

FIGURE 5.5 (a) Hyperphysic (net reduction) and (b) hypohypsic (net oxidation) hypsicity profiles. [Pg.106]

Total kernel raw material cost to produce 1 mol of target product Calculation of hypsicity (oxidation level) index... [Pg.114]

CYCLIZATION REACTIONS BY MINIMUM ATOM ECONOMY AND MAXIMUM ENVIRONMENTAL IMPACT FACTOR, MAXIMUM MOLECULAR WEIGHT FRACTION OF SACRIFICIAL REAGENTS, HYPSICITY INDEX... [Pg.183]


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Hypsicity (Oxidation Level) Analysis

Hypsicity Trends

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