2-hydroxyethyl sulfide

It also reacts with epoxides forming 2-hydroxyalkyl thiols, eg, 2-mercaptoethanol [60-24-2] and bis(2-hydroxyalkyl) sulfides such as bis (2-hydroxyethyl) sulfide [111-48-8], both products are made commercially ... 

Bis(2-diisopropylaminoethyl) Disulfide Bis(2-diisopropylaminoethyl) Sulfide Bis(2-fluoroethyl) 2-Chloroethylamine Bis(2-fluoroethyl)methylamine Bis(2-hydroxyethyl) Sulfide Bis(2-hydroxyethyl) Thioether Bis(2-hydroxyethyl)amine Bis(2-hydroxyethyl)methylamine Bis(2-propenyl) Sulfide Bis(bromomethyl) Ether Bis(chloromethyl) Ether Bis(cyclohexyl)carbodiimide Bis(ethenyl)sulfone Bis(trichloromethyl) Carbonate Bis(/3-bromoethyl) Sulfide Bis(/3-chloroethyl)ethylamine Bis(/3-Chloroethyl)methylamine Bis(/3-chloroethylthio)ethane Bis(/3-mercaptoethyl) Sulfide... 

In the case of cationic complexes with unsaturated macrocycles two molecules of nucleophile, such as ammonia, amines and alkoxides, add to carbon atoms of two inline groups. For example, the reaction of [Ni(Bzo[16]octaeneN4)](C104)2 (Table 106) with sodium methoxide or ethoxide yields the compounds (395),2860 while with secondary amines and diamines complexes of type (396) are obtained.28 1 The reaction of (396) with acetone at room temperature yields complex (397) where the enolate anion of acetone, MeC(0)CH2, replaces the diethylamide group (Scheme 58). 2862 The addition of molecules such as bis(2-hydroxyethyl)methylamine and bis(2-hydroxyethyl) sulfide, HOCH2CH2YCH2CH2OH (Y = NMe, S) results in the formation of derivatives which possess one more coordination site just above the plane of the macrocyclic donors (398).2863... 

Bis(2-ethylhexyl) sebacate, bl77 Bis(2-hydroxyethyl) sulfide, tl49... 

B.13 2. B.14 3. A.01 3.A.02 3.A.03 3.A.04 3.B.05 3.B.06 3.B.07 3.A.08 3.A.09 3.A.10 3.A.11 Bis(2-hydroxyethyl)sulfide 3,3-Dimethyl-2-butanol Carbonyl dichloride Cyanogen chloride Hydrogen cyanide Trichloronitromethane Phosphorous oxychloride Phosphorous trichloride Phosphorous pentachloride Trimethyl phosphate Triethyl phosphate Dimethyl phosphate Diethyl phosphate... 

Some of other effective platinum catalysts are sulfided platinum on carbon120 or platinum catalysts with inhibitors such as bis(2-hydroxyethyl)sulfide,121 morpholine,122 polyamines,123 phosphorous acid,105 phosphoric acid,124 and dicyandiamide.96 Dicy-andiamide was originally used as an effective inhibitor for Raney Ni, as described above (see eq. 9.50).113 Hydrogenations of halonitrobenzenes with use of these platinum catalysts are summarized in Table 9.5. In one patent, it is claimed that ethano-lamine is a better inhibitor than morpholine for Pt-C. Thus, 3,4-dichloronitrobenzene was hydrogenated over Pt-C modified with iron oxide in the presence of 1.2 mol% ethanolamine to give 3,4-dichloroaniline containing only 235 ppm of 4-chloroaniline, compared to 548 ppm with morpholine as the inhibitor.125... 

A solution of 122.2 g. (1.0 mole) of bis-2-hydroxyethyl sulfide ( Kromfax solvent. Carbide and Carbon Chemicals Corporation) and 978 g. of concentrated hydrochloric acid is heated under a reflux condenser to between 80° and 90° for 1 hour. (Use a good hood.) After the solution is cooled, the lower layer is separated and freed... 

BIS (2-HYDROXYETHYL)SULFIDE or BIS ( -HYDROXYETHYL)SULnDE (111-48-8) C4H10O2S Combustible liquid (flash point 320°F/160°C Fire Rating 1). Violent reaction with strong oxidizers, hydrochloric acid. Reacts with acids, forming hydrogen sulfide, a flammable and poisonous gas. Incompatible with aliphatic amines, bases, boranes, isocyanates. Flow or... 

Sng and Ng " compared several fiber materials for the in situ derivatization of metabolites of chemical munitions such as thiodiglycerol and ethyl-2-hydroxyethyl sulfide. 

For the separation of sulfur compounds on capillary columns, nonpolar GC phases are recommended. Phases such as crosslinked PDMS and (5%)-diphenyl-(95%)dimethyl siloxane materials have been used for ethyl-2-hydroxyethyl sulfide and thiodiglycerol, PASHs, thiophene, benzothiophenes, benzothiophene sulfones, VOCs, and screening analysis. 

---