1,4 Polybutadiene hydrogenation

Polyether-based thermoplastic copolyesters show a tendency toward oxidative degradation and hydrolysis at elevated temperature, which makes the use of stabilizer necessary. The problem could be overcome by incorporation of polyolehnic soft segments in PBT-based copolyesters [31,32]. Schmalz et al. [33] have proposed recently a more useful technique to incorporate nonpolar segments in PBT-based copolyesters. This involves a conventional two-step melt polycondensation of hydroxyl-terminated PEO-PEB-PEO (synthesized by chain extension of hydroxyl-terminated hydrogenated polybutadienes with ethylene oxide) and PBT-based copolyesters. 

The need to paint the blends has also resulted in new painting systems. Recently, a nonpolar color coat based on a hydrogenated polybutadiene diol and melamine resin for TPO bumper fascia was invented. The breakthrough technology allows the elimination of the TPO pretreatment step such as adhesion promoter, flame, or plasma during manufacturing. The paintability of two different types of E-plastomers was evaluated. The olefinic white paint was found to provide excellent paint adhesion for both types of metallocene plastomers. Paint peeling was not observed in any of the test... 

All values are with respect to that of reference polymer hydrogenated polybutadiene (HPB97), model ethylene-butene copolymer, x wt% butene. 

Figure 4 Plot of degree of crystallinity (XDSC) from DSC against crystallinity (Xp) determined by density measurements. (A), hydrogenated polybutadienes ( ), ethylene 1-butene copolymers ( ), ethylene 1-octene copolymers. Reprinted with permission from Ref. [72]. Copyright 1984 American Chemical Society. 

In this study, the effects of the variations in block sequence and composition (and thus relative block length) on the material properties of two series of triblock copolymers has been investigated. One of the blocks, the hydrogenated polybutadiene (HB), is semicrystalline, and the other block, the hydrogenated polyisoprene (HI) is rubbery at room temperature. Thus in one series, the HBIB block copolymers, the end blocks are semi-... 

Moisture embrittlement must be distinguished from other forms of embrittlement. Brittleness of propellants at low temperatures is normally caused by binders which stiffen excessively with decreasing temperatures, owing to partial crystallization of the binder matrix (e.g.9 copolymers of butadiene with acrylonitrile, some hydrogenated polybutadienes, etc.). Such propellants are brittle at low temperatures whether they have been exposed to moisture or not. 

Linear Polyethylene with Randomly Distributed Ethyl Branches (Hydrogenated Polybutadiene)... 

Fig. 18. Thermal equilibrium 13C NMR spectra for two hydrogenated polybutadiene samples P420 and P16, obtained by a r/2 single pulse sequence (ti/4-FID-t ) with t = 2000 s...

Fig. 22. Phase image of a thin film of a hydrogenated polybutadiene-polyethyleneoxide blockcopolymer (3700-2900 g/mol) on mica. The film was crystallised at 38 C close to a triple line caused by dewetting. Courtesy of G. Reiter [275]...

Figure 7.7 SAXS profiles for two hydroxyl-terminated oligomers crosslinked by alkoxysilane sol-gel chemistry. First, 1 mole of macrodiol, SS (hydrogenated polybutadiene, HPBD or polycaprolactone, PCL, Mn= 2 kg mol-1), was reacted at 80°C with 2 mole of dicyclohexylmethane diisocyanate, H12 MDI. After complete reaction, the prepolymer was dissolved in tetrahydro-furan and the y-aminosilane, yAPS was added dropwise at room temperature. After 1 h of reaction, the solvent was removed under pressure. The final network was obtained in the absence of a solvent by hydrolysis and condensation of the ethoxysilane groups by the addition of 0.1 mol% TFA, trifluor-oacetic acid. After stirring at room temperature, the mixture was cast into a mold and cured for 24 h at 100°C under pressure, and then postcured at 150°C for 12 h. (Cuney et al., 1997 - Copyright 2001, Reprinted by permission of John Wiley Sons, Inc.)...

FIG. 18.3 Activation energy of diffusion as a function of Tg for 21 different polymers from low to high temperatures, ( ) odd numbers (O) even numbers 1. Silicone rubber 2. Butadiene rubber 3. Hydropol (hydrogenated polybutadiene = amorphous polyethylene) 4. Styrene/butadiene rubber 5. Natural rubber 6. Butadiene/acrylonitrile rubber (80/20) 7. Butyl rubber 8. Ethylene/propylene rubber 9. Chloro-prene rubber (neoprene) 10. Poly(oxy methylene) 11. Butadiene/acrylonitrile rubber (60/40) 12. Polypropylene 13. Methyl rubber 14. Poly(viny[ acetate) 15. Nylon-11 16. Poly(ethyl methacrylate) 17. Polyethylene terephthalate) 18. Poly(vinyl chloride) 19. Polystyrene 20. Poly (bisphenol A carbonate) 21. Poly(2,6 dimethyl-p.phenylene oxide). 

Scheme 23.4 Repeat unit structures of polybutadiene and hydrogenated polybutadiene...

Experiments conducted on concentrated solutions of high molecular weight hydrogenated polybutadiene in a commercial oil [41] showed that the expected law... 

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