Hydrogen peroxide reaction with base

Synthesis. Symmetrical diacyl peroxides (20, R = R = alkyl or aryl) are prepared by the reaction of an acyl chloride or anhydride with sodium peroxide or hydrogen peroxide and a base ... 

Here A and B are non-luminescence molecules. The C is the excited state of the product C. Often these reactions involve oxidation reactions and the presence of a catalyst. Both chemical and biochemical reactions could generate the photon. The intensity of the photons are collected through optical fibers and measured with a photon detector. The most successful chemiluminescence sensor for the detection of the hydrogen peroxide [13] is based on luminol using ferricyanide as catalyst... 

Our approach utilized the metals gold, platinum, then later gold, platinum, and nickel electroplated in succession because the catalytic decomposition of hydrogen peroxide reaction we tested was most efficiently catalyzed with platinum.After fabrication of the nanowires they were freed by removing the conductive silver backing with nitric acid and the sacrificial template with a strong base, sodium hydroxide. Then nanorods were washed with deionized water and ultracentrifuged to achieve a neutral pH. 

Hydrogen peroxide reacts with ozone when present as anion, H02. The reaction rate of the system ozone/hydrogen peroxide is based on the initial concentration of both oxidants ... 

Thomas JK (1967) Pulse radiolysis of aqueous solutions of methyl iodide and methyl bromide. The reactions of iodine atoms and methyl radicals in water. J Phys Chem 71 1919-1925 Tsang W, Hampson RF (1986) Chemical kinetic data base for combustion chemistry, part I. Methane and related compounds. J Phys Chem Ref Data 15 1086-1279 UlanskiP, von Sonntag C (1999) The OFI-radical-induced chain reactions of methanol with hydrogen peroxide and with peroxodisulfate. J Chem Soc Perkin Trans 2 165-168 Ulanski P, Bothe E, Hildenbrand K, von Sonntag C, Rosiak JM (1997) The influence of repulsive electrostatic forces on the lifetimes of polyfacrylic acid) radicals in aqueous solution. Nukleonika 42 425-436... 

Thus, reactions of carbonyl compounds with hydrogen peroxide and acids lead to products similar to those obtained by the ozonization of olefins (Section III), which also yields 1,2,4-trioxolans and 1,2,4,5-tetroxans. The similarity of the two reactions is understandable, since the intermediates )C+—OO- in the ozonization27a and )C+—OOH in the hydrogen peroxide reactions are related as a conjugate base-acid pair. A number of cyclic peroxides of structure 7 are prepared from bis(hydroperoxy)dialkyl peroxides (5) by reaction with lead(IV) acetate, as described by Criegee et al.la This reaction is also thought to involve a carbonium ion intermediate,31 which reacts with the second OOH group. 

AMYL-METHYL-CETONE (French) (110-43-0) Forms explosive mixture with air (flash point 102°F/38°C). Violent reaction with strong oxidizers, aldehydes, nitric acid, perchloric acid. A variety of unstable peroxides may be formed from the reaction with hydrogen peroxide. Incompatible with aliphatic amines, aldehydes, strong bases, hydrogen peroxide, nitric acid, perchloric acid. Attacks some plastics and rubber. 

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