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Hydrogen, lithium reaction with

This solvent is preferred for the determination of active hydrogen by reaction with lithium aluminum hydride. For this use it is dried over calcium hydride, heated with LiAIH, for 2 hrs. at 90-100°, and then distilled at 20 mm. pressure. [Pg.925]

The hydrogenolyaia of cyclopropane rings (C—C bond cleavage) has been described on p, 105. In syntheses of complex molecules reductive cleavage of alcohols, epoxides, and enol ethers of 5-keto esters are the most important examples, and some selectivity rules will be given. Primary alcohols are converted into tosylates much faster than secondary alcohols. The tosylate group is substituted by hydrogen upon treatment with LiAlH (W. Zorbach, 1961). Epoxides are also easily opened by LiAlH. The hydride ion attacks the less hindered carbon atom of the epoxide (H.B. Henhest, 1956). The reduction of sterically hindered enol ethers of 9-keto esters with lithium in ammonia leads to the a,/S-unsaturated ester and subsequently to the saturated ester in reasonable yields (R.M. Coates, 1970). Tributyltin hydride reduces halides to hydrocarbons stereoselectively in a free-radical chain reaction (L.W. Menapace, 1964) and reacts only slowly with C 0 and C—C double bonds (W.T. Brady, 1970 H.G. Kuivila, 1968). [Pg.114]

The reaction of hydrogen and lithium readily gives lithium hydride [7580-67-8], LiH, which is stable at temperatures from the melting poiat up to 800°C. Lithium reacts with aitrogea, evea at ordiaary temperatures, to form the reddish browa nitride, Li3N. Lithium bums when heated in oxygen to... [Pg.223]

Sihca is reduced to siUcon at 1300—1400°C by hydrogen, carbon, and a variety of metallic elements. Gaseous siUcon monoxide is also formed. At pressures of >40 MPa (400 atm), in the presence of aluminum and aluminum haUdes, siUca can be converted to silane in high yields by reaction with hydrogen (15). SiUcon itself is not hydrogenated under these conditions. The formation of siUcon by reduction of siUca with carbon is important in the technical preparation of the element and its alloys and in the preparation of siUcon carbide in the electric furnace. Reduction with lithium and sodium occurs at 200—250°C, with the formation of metal oxide and siUcate. At 800—900°C, siUca is reduced by calcium, magnesium, and aluminum. Other metals reported to reduce siUca to the element include manganese, iron, niobium, uranium, lanthanum, cerium, and neodymium (16). [Pg.471]

The determination of position of protonation by reaction with diazomethane was performed as follows The enamine was treated at —70° with ethereal hydrogen chloride and the suspension of precipitated salt was treated with diazomethane and allowed to warm slowly to —40°, at which temperature nitrogen was liberated. The reaction with lithium aluminum hydride (LAH) was carried out similarly except that an ether solution of LAH was added in place of diazomethane. The results from reaction of diazomethane and LAH 16) are summarized in Table 1. [Pg.172]

Butyl alcohol in synthesis of phenyl 1-butyl ether, 46, 89 1-Butyl azidoacetate, 46, 47 hydrogenation of, 46, 47 1-Butyl chloroacetate, reaction with sodium azide, 46, 47 lre l-4-i-BUTYLCYCLOHEXANOL, 47,16 4-(-Butylcyclohexanonc, reduction with lithium aluminum hydride and aluminum chloride, 47, 17 1-Butyl hypochlorite, reaction with cy-clohexylamine, 46,17 l-Butylthiourea, 46, 72... [Pg.123]

Lithium has a moderate reaction with water when cold, but extremely violent when hot. The violent release of hydrogen along with a high temperature rise of the lithium particles sometimes provokes the gas to combust. With powdered lithium, an explosion will occur. [Pg.164]

Disilenes readily add halogens14,66 and active hydrogen compounds (HX), such as hydrogen halides,63,66 alcohols, and water,27 63 as well as hydride reagents, such as tin hydride and lithium aluminum hydride.66 These reactions are summarized in Scheme 9. The reaction of the stereo-isomeric disilene (E)-3 with hydrogen chloride and alcohols led to a mixture of E- and Z-isomers, but the reaction with chlorine gave only one of the two possible stereoisomers, thus indicating that the former two reactions proceed stepwise while the latter occurs without Si—Si rotation. [Pg.254]


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Hydrogenation reaction with

Reaction with hydrogen

Reaction with lithium

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