Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Hydrogen iodide preparation

Milder reductions with hydriodic acid can be accomplished by using more dilute hydriodic acid, or solutions of hydrogen iodide prepared from alkaline iodides and hydrochloric or acetic acid in organic solvents [22S],... [Pg.32]

Hydrogen iodide prepared by the hydrolytic decomposition of PI3 has been analysed by mass spectrometry and gas chromatography 187 it was found to contain hydrocarbon, halogenocarbon, and other impurities. According to Lerner and Cagliostro,188 HBr and HI are approximately equally effective as flame inhibitors for the air-C3H8 system. [Pg.489]

Hydrogen iodide is prepared in a similar way to hydrogen bromide, by the action of water on a mixture of iodine and violet phosphorus. TTie hydrogen iodide evolved may be collected by downward delivery or may be condensed (b.p. 238 K) it reacts with mercury and so cannot be collected over the latter. [Pg.333]

An aqueous solution of hydrogen iodide, up to 50% strength, may be prepared by passing hydrogen sulphide (or sulphur dioxide) into a suspension of iodine in water ... [Pg.333]

The hydrolysis of phosphorus tribromide or triiodide is used in the preparation of hydrogen bromide and hydrogen iodide respectively ... [Pg.345]

Hydrogen iodide. This gas may be conveniently prepared by allowing a solution of two parts of iodine in one part of hydriodic acid, sp. gr. 1 7 (for preparation, see Section 11,49,2), to drop on to excess of red phosphorus. The evolution of hydrogen iodide takes place in the cold when the evolution of gas slackens considerably, the mixture should be gently warmed. [Pg.182]

However, if an oxidising agent (fuming nitric acid or sodium persulphate) is present to destroy the hydrogen iodide as it is formed, the equilibrium is displaced and the iodo compound may be conveniently prepared, for example ... [Pg.533]

This preparation illustrates the direct iodination of a primary aromatic amine by iodine the sodium bicarbonate removes the hydrogen iodide as formed ... [Pg.647]

The ( )-vinylsilane 151 was prepared by treatment of the silylstannation product 150 with hydrogen iodide[75] and the silylzincation product with water[70]. The silylstannylation of 1-ethoxyacetylene proceeds at room temperature using Pd(OAc)i and 1,1,3,3-tetramethylbutyl isocyanide regioselec-tively and an Si group is introduced at the ethoxy-bearing carbon. Subsequent Cul- and Pd-catalyzed displacement of the stannyl group in the product 152 with allyl halide, followed by hvdrolvsis, affords the acylsilane 153[79],... [Pg.490]

The order of reactivity of the hydrogen halides parallels their acidity HI > HBr > HCl >> HF Hydrogen iodide is used infrequently however and the reaction of alco hols with hydrogen fluoride is not a useful method for the preparation of alkyl fluorides Among the various classes of alcohols tertiary alcohols are observed to be the most reactive and primary alcohols the least reactive... [Pg.152]

Hydroiodic acid, the colorless solution formed when hydrogen iodide gas dissolves in water, is prepared by reaction of iodine with hydrogen sulfide or hydrazine or by an electrolytic method. Typically commercial hydroiodic acid contains 40—55% HI. Hydroiodic acid is used in the preparation of iodides and many organic iodo compounds. [Pg.365]

Titanium tetraiodide can be prepared by direct combination of the elements at 150—200°C it can be made by reaction of gaseous hydrogen iodide with a solution of titanium tetrachloride in a suitable solvent and it can be purified by vacuum sublimation at 200°C. In the van Arkel method for the preparation of pure titanium metal, the sublimed tetraiodide is decomposed on a tungsten or titanium filament held at ca 1300°C (152). There are frequent hterature references to its use as a catalyst, eg, for the production of ethylene glycol from acetylene (153). [Pg.132]

Chemical Properties. The most significant chemical property of L-ascorbic acid is its reversible oxidation to dehydro-L-ascorbic acid. Dehydro-L-ascorbic acid has been prepared by uv irradiation and by oxidation with air and charcoal, halogens, ferric chloride, hydrogen peroxide, 2,6-dichlorophenolindophenol, neutral potassium permanganate, selenium oxide, and many other compounds. Dehydro-L-ascorbic acid has been reduced to L-ascorbic acid by hydrogen iodide, hydrogen sulfide, 1,4-dithiothreitol (l,4-dimercapto-2,3-butanediol), and the like (33). [Pg.13]

Zirconium monochloride and zirconium monobromide [31483-18-8] are prepared in better purity by equiUbration of mixed lower haUdes with zirconium foil at 625°C (184—185) or by slowly heating zirconium tetrahaUde with zirconium turnings at 400—800°C over a period of two weeks and hoi ding at 800—850°C for a few additional days (186). Similar attempts to produce zirconium monoiodide [14728-76-8] were unsuccesshil it was, however, obtained from the reaction of hydrogen iodide with metallic zirconium above 2000 K (187). [Pg.436]

A variation of the general method for the synthesis of 2-amino-selenazoles is to avoid the use of the free a-halogenocarbonyl compound and in its place react the corresponding ketone and iodine with selenourea.This procedure is also taken from thiazole chemistry. By contrast with thiourea, the reaction with selenourea needs a longer reaction time and the work up of the reaction mixture is somewhat more difficult. Usually an excess of the ketone is used. In the preparation of 2-amino-4-( n-nitrophenyl)selenazole, a very high yield, calculated on the amount of iodine used, was obtained. To explain this peculiar result, the oxidative action of the nitro group was invoked. This liberates free iodine from some of the hydrogen iodide eliminated in the condensation reaction, and the free iodine then re-enters into the reaction. [Pg.348]

Iodine can be prepared by allowing an aqueous solution of hydrogen iodide to react with manganese dioxide, Mn02. The reaction is... [Pg.576]

Benzene- 1,2-diacetonitriles e.g. 19, in the presence of hydrogen bromide in acetic acid, or in diethyl ether, cyclize to 4-bromo-l //-3-benzazepin-2-amines, e.g. 20a.41,42 l//-Naphtho[2,3-t/]azepines, e.g. 22a, are prepared in a similar manner from naphthalene-2,3-diacetonitriles, e.g. 21.41 Replacement of hydrogen bromide by hydrogen iodide yields the corresponding 4-iodo derivatives, e.g. 20b and 22b. [Pg.214]

There have been several accidents with metalloids detonation with fluorine very violent reaction with boron at 700°C, and ignition with white phosphorus. In the last case, the dangerous character of the reaction of the preparation of hydrogen iodide by distillation of the phosphorus/moist iodide mixture was also mentioned. The formation of phosphonium iodide often causes the conduits of the apparatus to block, which causes the apparatus to detonate due to overpressure. Several accidents involve this factor, which is not due to a reaction that is intrinsically dangerous. [Pg.227]

Among the most useful compounds of the halogens are the hydrogen halides. Hydrogen iodide is not very stable, and it cannot be efficiently prepared by direct combination of the elements. Rather, as is... [Pg.555]

Fluorescein (147) is prepared by the same route as Pigment Red 90 (see p. 575). The compound is iodized with iodine and potassium iodate in an acidic medium. The iodic acid reoxidizes the resulting hydrogen iodide back to iodine ... [Pg.567]

The first reaction proceeds most easily with hydrogen iodide since in many cases mere saturation with the gaseous acid suffices to bring it about. Hydrogen bromide reacts with greater difficulty, and in its case it is frequently necessary to heat the alcohol saturated with this acid in a sealed tube. The preparation of ethyl bromide described above, in which the HBr is liberated from the potassium bromide by means of concentrated sulphuric acid, constitutes a very smooth example of this reaction. [Pg.96]


See other pages where Hydrogen iodide preparation is mentioned: [Pg.165]    [Pg.210]    [Pg.284]    [Pg.365]    [Pg.366]    [Pg.139]    [Pg.229]    [Pg.86]    [Pg.13]    [Pg.227]    [Pg.284]    [Pg.37]    [Pg.34]    [Pg.12]    [Pg.140]    [Pg.243]    [Pg.38]    [Pg.69]   
See also in sourсe #XX -- [ Pg.72 ]




SEARCH



Hydrogen iodid

Hydrogen iodide

Hydrogen preparation

Iodide preparation

© 2024 chempedia.info