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Hydrocarbon derivatives polarity

The reaction takes place at low temperature (40-60 °C), without any solvent, in two (or more, up to four) well-mixed reactors in series. The pressure is sufficient to maintain the reactants in the liquid phase (no gas phase). Mixing and heat removal are ensured by an external circulation loop. The two components of the catalytic system are injected separately into this reaction loop with precise flow control. The residence time could be between 5 and 10 hours. At the output of the reaction section, the effluent containing the catalyst is chemically neutralized and the catalyst residue is separated from the products by aqueous washing. The catalyst components are not recycled. Unconverted olefin and inert hydrocarbons are separated from the octenes by distillation columns. The catalytic system is sensitive to impurities that can coordinate strongly to the nickel metal center or can react with the alkylaluminium derivative (polyunsaturated hydrocarbons and polar compounds such as water). [Pg.272]

Schuetzle, D T. E. Jensen, and J. C. Ball, Polar Polynuclear Aromatic Hydrocarbon Derivatives in Extracts of Particulates Biological Characterization and Techniques for Chemical Analysis, Enriron. Int., 11, 169-181 (1985). [Pg.542]

Hydrocarbons consist entirely of nonpolar C-H bonds with no unpaired electrons. These compounds are relatively unreactive. The substitution of one or more atoms with unpaired electrons into the hydrocarbon backbone creates a hydrocarbon derivative. The unpaired electrons result in polar or charged portions of these molecules. These atoms fall into categories known as functional groups, and they create local regions of reactivity. Alkyl, alkenyl, alkynyl, and aryl groups may also be considered functional groups in some circumstances as described in the previous skill. [Pg.142]

As previously described, friction modifiers are usually long slender molecules with a straight hydrocarbon chain of at least ten carbon atoms. Hydrocarbons derived from natural products are ideal for such applications. The polar head group is the dominant factor in the effectiveness of the molecule as a friction modifier, such polar groups consist of ... [Pg.193]

There are seven hydrocarbon-derivative families whose primary hazard is flammability (see Chapter 2, Figure 2.63) alkyl halide, amine, ether, alcohol, ketone, aldehyde, and ester. The alkyl halides, amines, and ethers are nonpolar. The ethers, alcohols, and aldehydes are polar and have wide flammable ranges. Some organic acids are flammable inorganic acids do not bum. However, flammability is not the primary hazard of most organic acids. They will be discussed in detail in Chapter 10. [Pg.198]

Acetone, also known as dimethyl ketone, is a ketone hydrocarbon derivative. It is a colorless, volatile liquid with a sweetish odor. Acetone is a carbonyl, is polar. [Pg.212]

Vinyl acetate is an ester hydrocarbon-derivative compound. It is a colorless liqnid that has been stabilized with an inhibitor. Although it is a polar compound becanse of the carbonyl structure, it is only shghtly miscible in water. Vinyl acetate is a highly flammable hquid, with a flammable range of 2.6 to 13.4% in air, and it... [Pg.218]

An algae-derived oil was reported to be principally n-paraffins and olefins with oxygen- and nitrogen-containing straight-chain hydrocarbons (5 ). Polar compounds were reported to comprise 50-60 percent of the oil. Unfortunately, there is no indication of the type of analysis performed or detailed results of any kind therefore, it is difficult to evaluate the veracity of these reported results. [Pg.181]


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