Inorganic hydrides

Reilly, J. J. and Wiswall, R. H., Formation and Properties of Iron Titanium Hydride, Inorganic Chem, 1974 13, 218. 

Addamo, M., Bombieti, G, Foresti, E., Grillone, M.D., and Volpe, M. (2004) Assembling process of charged nonanuclear cationic lanthanide(lll) clusters assisted by dichromium decacarbonyl hydride. Inorganic Chemistry, 43, 1603—1605. 

Reilly, J. and Wiswall, R.H., Formations and properties of iron titanium hydride. Inorganic Chemistry, 1974, 13 p. 218. 

LiAlH4, lithium tetrahydridoaluminate ("lithium aluminium hydride . so-called) is an excellent reducing agent in ether solution for both organic and inorganic compounds it may be used to prepare covalent hydrides SiH ether, for example... 

G. D. James, Rec. Chem. Prog. 31, 199 (1970). Inorganic chemistry of complex hydrides. 

Oxidation. AH inorganic siUcon hydrides are readily oxidized. Silane and disilane are pyrophoric in air and form siUcon dioxide and water as combustion products thus, the soot from these materials is white. The activation energies of the reaction of silane with molecular and atomic oxygen have been reported (20,21). The oxidation reaction of dichlorosilane under low pressure has been used for the vapor deposition of siUcon dioxide (22). 

Thorium is potentially hazardous. Einely divided thorium metal and hydrides can be explosive or inflammatory hazards with respect to oxygen and halogens. Einely divided Th02 and other inorganic salts also present an inhalation and irritation hazard. The use of standard precautions, skin covering, and a conventional dust respirator should be sufficient for handling thorium materials. 

Boron Hydrides and Related Compounds," in, G. L. Leigh, ed., Nomenclature of Inorganic Chemist, Becommendations 1990, lUPAC, Oxford, UK, 1990, Chapt. I-ll. 

GAS CHROMATOGRAPHIC - MASS SPECTROMETRIC DETERMINATION OF INORGANIC HYDRIDES, PERMANENT GASES AND HYDROCARBONS IN HIGH PURITY SILANE... 

A solution of 3jS-hydroxy-5a-androstan-17-one tosylate (193, 60 mg) in tetrahydrofuran (10 ml, freshly distilled from lithium aluminum hydride) is added dropwise to a boiling suspension of lithium aluminum deuteride (60 mg) in tetrahydrofuran (10 ml). The resulting suspension is heated under reflux for 30 min and after cooling the excess reagent is decomposed by the careful addition of a few drops of water. The heating is continued for a few minutes to coagulate the inorganic salts which are removed by filtration... 

A mixture of 6/l-chloroandrost-4-ene-3/ ,17/l-diol dibenzoate (223 1.5 g) and lithium aluminum deuteride (0.5 g) in anhydrous ether (75 ml) is heated under reflux for 2 hr and then stirred overnight at room temperature. The excess hydride is decomposed by the careful addition of saturated sodium sulfate solution, and the inorganic salts are removed by filtration and washed with... 

The dry tosylhydrazone (20 g, 45.5 mmol) is dissolved in 750 ml of 1,2-dimethoxyethane (freshly distilled from lithium aluminum hydride) in a flame-dried 1 liter round bottom flask fitted with a 240 ml addition funnel, a drierite tube and a magnetic stirrer. A 2.05 M ether solution of methyllithium (130 ml, Alfa Inorganics, Inc.—Caution to avoid the mineral oil impurity the methyllithium solution is decanted from a cold solution which contains a precipitate) is placed in the dropping funnel and added over a 60 min period. The temperature of the reaction mixture increases to ca. 35° during the addition however, no cooling precautions are required. The highly colored reaction mixture is stirred for 7 hr and then poured into 1.5 liters of ice water. The flocculent precipitate is digested for 12 hr at room temperature to speed the filtration. After filtration the filter cake is washed with 500 ml water and dried under vacuum at 50° for several hr. The androsta-5,16-dien-3l5-ol is obtained in ca. 70% yield after recrystallization from methanol mp 138-139°. 

K. M. Mackay, Hydrogen Compounds of the Metallic Elements, E. and F. N. Spon, London, 1966, 168 pp. Hydrides, Comprehensive Inorganic Chemistry, Vol. 1, Chap. 2, Pergamon Press, Oxford, 1973. 

I. Sodium hydride, 50% dispersion in mineral oil Alpha Inorganics Ethyl chloroformate EK, MCB... 

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