Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Hilbert relation

By taking the real and imaginary parts of this last integral representation one obtains the Hilbert relations, which in physical applications have become known under the name dispersion relations ... [Pg.591]

If the transfer function H is in accordance with the causality rule, the components R and X are no longer independent of each other. Causality in the meaning of system theory forces couplings between the real and imaginary part, which are known as Kramers-Kronig relations (KKT) or Hilbert relations (HT), for details see Section 3.1.2.9 (The use of Kramers-Kronig Transforms). [Pg.502]

By assuming the Hilbert space of dimension N, one can easily establish the relation between coupling matrices and by considering tbe (i/)tb matrix element of V ... [Pg.85]

The sign alternatives depend on the location of the zeros (or singulai ities) of x i). The above conjugate, or reciprocal, relations aie the main results in this section. When Eqs. (9) and (10) hold, ln x(f) and argx(t) are Hilbert transforms [245,246]. [Pg.113]

In case of three conical intersections, we have as many as eight different sets of eigenfunctions, and so on. Thus we have to refer to an additional chai acterization of a given sub-sub-Hilbert space. This characterization is related to the number Nj of conical intersections and the associated possible number of sign flips due to different contours in the relevant region of configuration space, traced by the electronic manifold. [Pg.667]

The question to be asked is Under what conditions (if at all) do the components of X fulfill Eq. (B.8) In [34] it is proved that this relation holds for any full Hilbert space. Here, we shall show that this relation holds also for the P sub-Hilbert space of dimension M, as defined by Eq. (10). To show that we employ, again, the Feshbach projection operator foraialism [79] [see Eqs. (11)]. [Pg.719]

Note that relations (1.91) and (1.92) mean linearity of the duality mapping I and its inverse I in Hilbert spaces due to the linearity of the scalar product. [Pg.35]

The second axiom, which is reminiscent of Mach s principle, also contains the seeds of Leibniz s Monads [reschQl]. All is process. That is to say, there is no thing in the universe. Things, objects, entities, are abstractions of what is relatively constant from a process of movement and transformation. They are like the shapes that children like to see in the clouds. The Einstein-Podolsky-Rosen correlations (see section 12.7.1) remind us that what we empirically accept as fundamental particles - electrons, atoms, molecules, etc. - actually never exist in total isolation. Moreover, recalling von Neumann s uniqueness theorem for canonical commutation relations (which asserts that for locally compact phase spaces all Hilbert-space representations of the canonical commutation relations are physically equivalent), we note that for systems with non-locally-compact phase spaces, the uniqueness theorem fails, and therefore there must be infinitely many physically inequivalent and... [Pg.699]

We must next consider more precisely the connection between the description of bodily identical states by the two observers (the requirements of Postulate 1). Quite in general, in fact, a physical theory, and quantum electrodynamics in particular, is fully defined only if the connection between the description of bodily identical states by (equivalent) observers is known for every state of the system and for every pair of observers. Since the observers are equivalent every state which can be described by 0 can also be described by O. Given a bodily state of the same system, observer 0 will ascribe to it a state vector Y0> in his Hilbert space and observer O will attribute to it a state vector T0.) in his Hilbert space. The above formulation of invariance means that there exists a one-to-one correspondence between the vectors Y0> and Y0.) used by observers 0 and O to describe bodily the same state.3 This correspondence guarantees that the two Hilbert spaces are in fact isomorphic. It is, therefore, possible for the two observers to agree to describe states of the system by vectors in the same Hilbert space. A similar statement can be made for the observables there exists a one-to-one correspondence between the operators Q0 and Q0>, which observers 0 and O attribute to observables. The consistency of the theory (Postulate 2) demands, however, that the two observers make the same prediction as the outcome of the same experiment performed on bodily the same system. This requires the relation... [Pg.667]

Rate of change of observables, 477 Ray in Hilbert space, 427 Rayleigh quotient, 69 Reduction from functional to algebraic form, 97 Regula fold method, 80 Reifien, B., 212 Relative motion of particles, 4 Relative velocity coordinate system and gas coordinate system, 10 Relativistic invariance of quantum electrodynamics, 669 Relativistic particle relation between energy and momentum, 496 Relativistic quantum mechanics, 484 Relaxation interval, 385 method of, 62 oscillations, 383 asymptotic theory, 388 discontinuous theory, 385 Reliability, 284... [Pg.782]

A final example is the concept of QM state. It is often stated that the wave function must be square integrable because the modulus square of the wave function is a probability distribution. States in QM are rays in Hilbert space, which are equivalence classes of wave functions. The equivalence relation between two wave functions is that one wave function is equal to the other multiplied by a complex number. The space of QM states is then a projective space, which by an infinite stereographic projection is isomorphic to a sphere in Hilbert space with any radius, conventionally chosen as one. Hence states can be identified with normalized wave functions as representatives from each equivalence class. This fact is important for the probability interpretation, but it is not a consequence of the probability interpretation. [Pg.26]

In the two-electronic-state Born-Huang expansion, the full-Hilbert space of adiabatic electronic states is approximated by the lowest two states and furnishes for the corresponding electronic wave functions the approximate closure relation... [Pg.308]

Let X be a smooth projective variety of dimension d over a field k. For d > 3 and n > 4 the Hilbert scheme Xl" is singular. However X 3 is smooth for all d IN. In this section we want to compute the Betti numbers of X can be viewed as a variety of unordered triangles on X. We also consider a number of other varieties of triangles on X, some of which have not yet appeared in the literature. As far as this is not yet known, we show that all these varieties are smooth. We study the relations between these varieties and compute their Betti numbers using the Weil conjectures. [Pg.60]

Consider, furthermore, a (2i- - 1)-dimensional subspace of the Hilbert space with fixed 5. Then, according to Schwinger s theory of angular momentum [98], this discrete spin DoF can be represented by two bosonic oscillators described by creation and annihilation operators with commutation relations... [Pg.302]

The mapping preserves the commutation relations (70) of the spin operators. As can be seen from (75d), the image of the 2s + 1)-dimensional spin Hilbert space is the subspace of the two-oscillator Hilbert space with 2s quanmm of excitation— the so-called physical subspace [218, 220], This subspace is invariant under the action of any operator which results by the mapping (75a)-(75d) from an arbitrary spin operator A(5 i, S2, S3). Thus, starting in this subspace the system will always remain in it. As a consequence, the mapping yields the following identity for the matrix elements of an operator A ... [Pg.303]

Let us briefly mention some formal aspects of the above-introduced formalism, which have been discussed in detail by Blaizot and Marshalek [218]. First, it is noted that the both the Schwinger and the Holstein-Primakoff representations are not unitary transformations in the usual sense. Nevertheless, a transformation may be defined in terms of a formal mapping operator acting in the fermionic-bosonic product Hilbert space. Furthermore, the interrelation of the Schwinger representation and the Holstein-Primakoff representation has been investigated in the context of quantization of time-dependent self-consistent fields. It has been shown that the representations are related to each other by a nonunitary transformation. This lack of unitarity is a consequence of the nonexistence of a unitary polar decomposition of the creation and annihilation operators a and at [221] and the resulting difficulties in the definition of a proper phase operator in quantum optics [222]. [Pg.304]

Question 9.6. Let V be the tautological bundle over the Hilbert scheme (C ) of C. How the correspondence P pt][i] acts on Chern classes Cfc(V) This question should relate to Question 4.12. [Pg.97]

I now consider statement 3 How should an extension of dynamics be understood In the MPC theory the problem does not exist For the intrinsically stochastic systems there is no need for modifying the laws of dynamics. As for the LPS theory, one notes the presence of two essentially new concepts. The introduction of non-Hilbert functional spaces only concerns the definition of the states of the dynamical system, and not at all the law governing their evolution. It is an important precision introduced in statistical mechanics. The extension of dynamics thus only appears in the operation of regularization of the resonances. This step is also the one that is most difficult to justify rigorously it is related to the (practical) necessity to use perturbation calculus (see Appendix). [Pg.23]

The column vector is indicated by square brackets, a row vector by round brackets. The quantum numbers may be determined by the complete set of her-mitian operators commuting with the generator of time evolution. Invariance of the quantum state to frame rotation, origin displacement, parity and other symmetry operations determine quantum numbers for the corresponding irreducible representations. Frame related symmetry operations translate into unitary operator acting on Hilbert space (rigged), e.g. Ta. [Pg.179]

This method is based on the Kramers-Kronig relation (1), saying that both s and e" carry the same information about relaxation processes and are related by a Hilbert transformation ... [Pg.116]

Physicist P. A. M. Dirac suggested an inspired notation for the Hilbert space of quantum mechanics [essentially, the Euclidean space of (9.20a, b) for / — oo, which introduces some subtleties not required for the finite-dimensional thermodynamic geometry]. Dirac s notation applies equally well to matrix equations [such as (9.7)-(9.19)] and to differential equations [such as Schrodinger s equation] that relate operators (mathematical objects that change functions or vectors of the space) and wavefunctions in quantum theory. Dirac s notation shows explicitly that the disparate-looking matrix mechanical vs. wave mechanical representations of quantum theory are actually equivalent, by exhibiting them in unified symbols that are free of the extraneous details of a particular mathematical representation. Dirac s notation can also help us to recognize such commonality in alternative mathematical representations of equilibrium thermodynamics. [Pg.324]

Going back to the example given at the beginning and noting that every closed subscheme X c Pr with Hilbert polynomial equal to (t+n) is a linear subspace of dimension n < >, we see that the incidence relation has the above defined universal property with respect to p(t) (t+n) , hence... [Pg.80]

The Hilbert schemes can therefore be considered as generalizations of the grassmannians, and the universal families as generalizations of the incidence relations. [Pg.80]


See other pages where Hilbert relation is mentioned: [Pg.95]    [Pg.639]    [Pg.707]    [Pg.43]    [Pg.670]    [Pg.199]    [Pg.770]    [Pg.838]    [Pg.1]    [Pg.81]    [Pg.116]    [Pg.145]    [Pg.212]    [Pg.3]    [Pg.70]    [Pg.263]    [Pg.308]    [Pg.179]    [Pg.3]    [Pg.3]    [Pg.70]    [Pg.443]   
See also in sourсe #XX -- [ Pg.502 ]




SEARCH



Kramers-Kronig relations Hilbert transform

© 2024 chempedia.info